Objective
The objective of this project is to gain control on the mechanism of transport properties of Self Assembled Monolayer (SAM)-based molecular tunnel junctions. The methodology developed by the Whitesides group over the last few years has allowed to increase the reliability of molecular tunnel junctions, allowing to measure their tunnel transport rates with much more accuracy than it had been possible until now, demonstrating how SAMs of alkylthiolates on Ag with odd or even number of atoms show different conductivities. The Whitesides group has also demonstrated the efficient rectification of Fc-terminated SAMs and suggested a mechanism to explain this result. In this project, we propose to rationally engineer the orbital energies of SAMs terminal groups in order to obtain predictable tunneling and/or hopping behaviors. The good development of this project will require the fellow to identify the target molecules by Ab Initio calculations, to engage in organic synthesis to prepare them, and to use a wide range of material science techniques to prepare, characterize and analyze the transport properties of their SAMs. The knowledge acquired by the fellow in Prof. Whitesides group in Harvard will then be transferred to the use of tunnel junctions bearing molecular magnetic end-groups, including SIngle Molecule Magnets, and potentially allowing to design and prepare highly magnetoresistive junctions. The outcome of this work would on one hand improve the fundamental knowledge on molecular tunnel junctions, potentially allowing to use them for molecular electronics, and could provide highly functional molecular spintronics devices by fine tuning of their spin injection barriers.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: https://op.europa.eu/en/web/eu-vocabularies/euroscivoc.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: https://op.europa.eu/en/web/eu-vocabularies/euroscivoc.
- natural sciences chemical sciences inorganic chemistry post-transition metals
- natural sciences physical sciences electromagnetism and electronics spintronics molecular spintronics
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Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
FP7-PEOPLE-2012-IOF
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Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
75794 Paris
France
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.