Objective Inspired by the diverse functionalities of complex molecular building blocks evidenced in manifold life processes as transport of respiratory gases, metabolism or light harvesting, we aim for a comprehensive characterization and control of molecular properties in surface-based model systems. To fully exploit and tune molecular functionality on substrates, a paradigm shift away from conventional metal supports, which might drastically affect adsorbates, is mandatory. We propose to apply nanostructured boron nitride (BN) monolayers and sp2-heterostructures as templates for molecular units and architectures. As indicated by the fascinating nanomesh interface and the electronically corrugated atomically thin BN sheet on Cu we recently reported, inert, temperature stable and insulating BN has a huge potential as advanced substrate supporting molecular functionality, self-ordering and intercalation.By combining the inherent functionality of organic or bio-molecular building blocks with the unusual electronic and structural characteristics of advanced sp2-bonded substrates grown by chemical vapour deposition, we aim to achieve desired properties, including electronic, magnetic and conformational switching, tunable reactivity, or tailored electronic band gaps. Special emphasis will be put on economic substrates as thin films or foils, which open perspectives for scalable processing.With this proposal, we wish to establish research at the interface of surface science, supramolecular chemistry and materials engineering, yielding new insight into physicochemical processes at the single-molecule level, but also offering pathways to molecular sensors, switches, catalysts and devices, thus making a viable contribution to the on-going quest for innovation in nanotechnology. State-of-the-art scanning probe microscopy, a proposed new apparatus for the growth and handling of sp2-sheets and complementary X-ray based techniques will be used to tackle this ambitious project. Fields of science engineering and technologynanotechnologynatural sciencesphysical sciencesopticsmicroscopyengineering and technologymaterials engineeringcoating and filmsnatural scienceschemical sciencescatalysisnatural scienceschemical sciencesinorganic chemistrymetalloids Programme(s) FP7-IDEAS-ERC - Specific programme: "Ideas" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013) Topic(s) ERC-CG-2013-PE4 - ERC Consolidator Grant - Physical and Analytical Chemical Sciences Call for proposal ERC-2013-CoG See other projects for this call Funding Scheme ERC-CG - ERC Consolidator Grants Host institution TECHNISCHE UNIVERSITAET MUENCHEN EU contribution € 1 983 841,00 Address Arcisstrasse 21 80333 Muenchen Germany See on map Region Bayern Oberbayern München, Kreisfreie Stadt Activity type Higher or Secondary Education Establishments Administrative Contact Ulrike Ronchetti (Mrs.) Principal investigator Wilhelm Auwärter (Dr.) Links Contact the organisation Opens in new window Website Opens in new window Total cost No data Beneficiaries (1) Sort alphabetically Sort by EU Contribution Expand all Collapse all TECHNISCHE UNIVERSITAET MUENCHEN Germany EU contribution € 1 983 841,00 Address Arcisstrasse 21 80333 Muenchen See on map Region Bayern Oberbayern München, Kreisfreie Stadt Activity type Higher or Secondary Education Establishments Administrative Contact Ulrike Ronchetti (Mrs.) Principal investigator Wilhelm Auwärter (Dr.) Links Contact the organisation Opens in new window Website Opens in new window Total cost No data