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PHOto-induced Energy flow in Bio-inspired molecular circuits probed with Ultrafast two-dimensional Spectroscopy

Objective

Solar energy is forecast to cover an important fraction of the world’s energy necessities over the next century. The energy captured from sunlight will be used to drive photovoltaic cells or to produce solar fuels, thus Scientists must learn how to harvest, transfer and store it efficiently. In this framework, the PHOEBUS project aims at providing the design of innovative chemical structures (molecular circuits) that can control in sophisticated ways the flow of excitation energy.
The project focuses on bio-inspired molecular circuits, where several light-absorbing molecules are linked together to form antenna systems displaying ultrafast electronic energy transfer (EET). We aim to identify and understand how coherent effects can direct, control, and optimize energy flow after photo-excitation. PHOEBUS will answer to the following questions: (i) does coherence radically change excitation transport compared to incoherent hopping of excitation? (ii) how can we design chemical structures that use coherence in light harvesting? Two-dimensional electronic spectroscopy (2DES) is the ideal experimental tool to track EET and unveil coherent couplings in multi-chromophoric complexes. This optical technique is at the frontier of ultrafast spectroscopy. We will develop a 2DES apparatus using sub-10fs optical pulses and we will use it to determine the quantum-chemical rules guiding ultrafast EET in these innovative systems. The combination of femtosecond nonlinear spectroscopy, quantum chemical calculations, and chemical synthesis will contribute to the ultimate ambitious goal of changing the way artificial light-harvesting technologies are designed.

Fields of science (EuroSciVoc)

CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: https://op.europa.eu/en/web/eu-vocabularies/euroscivoc.

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Programme(s)

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Topic(s)

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Funding Scheme

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MSCA-IF-GF - Global Fellowships

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Call for proposal

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(opens in new window) H2020-MSCA-IF-2014

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Coordinator

POLITECNICO DI MILANO
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 244 269,00
Address
PIAZZA LEONARDO DA VINCI 32
20133 Milano
Italy

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Region
Nord-Ovest Lombardia Milano
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 244 269,00

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