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Catalytic C–F Bond Functionalization for the Fixation of Environmentally Persistent Fluorocarbons

Objective

The objective of my project is to develop new methods to transform environmentally persistent hydrofluorocarbons (HFCs) and hydrofluoroolefins (HFOs), into reactive chemical building blocks that can be used in chemical manufacture. My team will achieve this by developing a series of new chemical reactions that transform inert carbon–fluorine bonds in HFCs or HFOs into reactive carbon–boron or carbon–aluminum bonds. My team will show that these reactive species can be used to construct carbon–carbon bonds. The idea is to develop a net series of reactions that results in the fixation of fluorine from low-value, volatile, and environmentally damaging organic molecules to high-value, non-volatile organic molecules. When successful, this approach should open up new routes that allow the chemical industry to repurpose HFCs and HFOs as chemical intermediates, and not end products, that complements European Union legislation. By the end of this project, my team will have pioneered methods for the production of agrochemicals and pharmaceuticals from environmentally persistent fluorocarbons.

Fields of science (EuroSciVoc)

CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: https://op.europa.eu/en/web/eu-vocabularies/euroscivoc.

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Host institution

IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE
Net EU contribution
€ 1 496 925,00
Address
SOUTH KENSINGTON CAMPUS EXHIBITION ROAD
SW7 2AZ LONDON
United Kingdom

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Region
London Inner London — West Westminster
Activity type
Higher or Secondary Education Establishments
Links
Total cost
€ 1 496 925,00

Beneficiaries (1)