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Low Coordinate Transition Metal Single Molecule Magnets

Objective

The Fellow, Maialen Espinal (MEV) from the University of Bath, outlines a case for support to work alongside the Host, Prof Mike Whittlesey (MKW: University of Bath, UK), on the design of novel two-coordinate complexes of Ni, Co and Fe as single molecule magnets (SMMs).The rationale for the work is the 2013 report by the MKWs group of a cationic Ni(I) N-heterocyclic carbene complex that exhibited the first example of SMM behavior observed in a mononuclear Ni complex. SMMs are the focus of considerable multidisciplinary investigations because of their potential for high-density information storage and quantum computing. Most work until now has focussed on lanthanides, but there has been an increasing realisation that organotransition metal derived SMMs may offer significant benefits in terms of their ability to stabilise different electronic environments as a result of being able to adopt unique coordination geometries. MEVs approach will be to use large ring NHC ligands and probe the influence of ring size, substituents, coordination mode and resulting molecular geometry on magnetic behaviour. The project will utilise the research experience of the applicant in synthetic chemistry to make new compounds in Bath, but most importantly, provide her a unique opportunity to develop new skills for progression of her career by exposure to new techniques and methodologies through periods of secondment to internationally leading laboratories for studies of magnetism (Prof Annie Powell (AKP), Karlsruhe, Germany), paramagnetism via Electron Paramagnetic Resonance (Prof Damien Murphy (DMM), Cardiff, UK) and computational chemistry (Prof Stuart Macgregor (SAM), Heriot-Watt, UK).

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Topic(s)

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MSCA-IF-EF-ST - Standard EF

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Call for proposal

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(opens in new window) H2020-MSCA-IF-2015

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Coordinator

UNIVERSITY OF BATH
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 183 454,80
Address
CLAVERTON DOWN
BA2 7AY BATH
United Kingdom

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Region
South West (England) Gloucestershire, Wiltshire and Bristol/Bath area Bath and North East Somerset, North Somerset and South Gloucestershire
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 183 454,80
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