Objectif The goal of this proposal is to quantify the rates and processes of sulphide oxidation in coastal sediments. The marine sulphur cycle is driven by the reduction of sulphate to sulphide coupled to microbial decomposition of organic matter, a process which is responsible for up to 50 % of carbon mineralisation in coastal sediment and is intimately connected to earth’s biogeochemical evolution. The sulphide produced by sulphate reduction may either react with Fe to be buried as pyrite or may be oxidised through different pathways and intermediates. The amount of sulphide that is oxidised in marine sediments is not known, yet oxidative sulphur cycling has critical implications for estimates of sulphate reduction, sub-seafloor carbon mineralisation, methane oxidation, microbial metabolism and the interpretation of ancient and modern stable isotope signatures. Quantification of oxidative sulphur cycling, including sulphide oxidation rates, the formation of key intermediate species and associated stable isotope effects is therefore fundamental to our understanding of sub-seafloor biogeochemistry. The research proposed herein will address these yet unanswered questions through a novel combination of radiotracer experiments, stable isotope measurements, and analyses of inorganic sulphur speciation. This approach will be applied to (1) quantify rates of concurrent sulphate reduction and sulphide oxidation in coastal sediment, (2) quantify the formation of intermediate species formed during sulphide oxidation and (3) measure stable isotope effects associated with oxidative sulphur cycling. This work will result in a more accurate description of sediment biogeochemistry by resolving current debates regarding the role of sulphur for carbon mineralisation ad further constraining processes which affect the sulphur stable isotope distribution. Champ scientifique natural sciencesearth and related environmental sciencesphysical geographycoastal geographynatural scienceschemical scienceselectrochemistryelectrolysisnatural sciencesearth and related environmental scienceshydrologynatural scienceschemical sciencesorganic chemistryaliphatic compoundsnatural sciencesearth and related environmental sciencesgeochemistrybiogeochemistry Programme(s) H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions Main Programme H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility Thème(s) MSCA-IF-2016 - Individual Fellowships Appel à propositions H2020-MSCA-IF-2016 Voir d’autres projets de cet appel Régime de financement MSCA-IF-EF-ST - Standard EF Coordinateur AARHUS UNIVERSITET Contribution nette de l'UE € 200 194,80 Adresse NORDRE RINGGADE 1 8000 Aarhus C Danemark Voir sur la carte Région Danmark Midtjylland Østjylland Type d’activité Higher or Secondary Education Establishments Liens Contacter l’organisation Opens in new window Site web Opens in new window Participation aux programmes de R&I de l'UE Opens in new window Réseau de collaboration HORIZON Opens in new window Coût total € 200 194,80