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Contenuto archiviato il 2022-12-23

Investigation of 129Xe and fission Xe in the terrestrial atmosphere and lithosphere: implications for the evolution of the Earth's atmosphere

Obiettivo



Since 1963 alien xenon enriched in the isotopes 132Xe, 131Xe, 134Xe, 129Xe has been observed in CO2 well gases, MORB (Mid-Ocean-Ridge Basalt) glasses basalt, anorthosite from Greenland, and in meteorites. The surprising similarity of the xenon isotopic composition in these distinctly different objects was noted but no explanation has been suggested. Recently, the hypothesis was put forward that the enrichment of the middle isotopes may result from the migration of beta-radioactive precursors produced during the fission of heavy nuclei.

The migration of Xe precursors occurred at a relatively high temperature and/or in outer parts of mineral grains. Some experimental evidence of such mechanisms resulted from the analyses of Xe in rocks from the Oklo natural nuclear reactor, of Xe evolved in the ampoule during neutron irradiation of pitchblends, and of Xe in the sandstone from the epicentre of a nuclear test. Because of the proposed origin of alien xenon it was subsequently called CFF-Xe (Chemically Fractionated Fission Xe), but further development and testing of the formation hypothesis is needed.

This project aims to improve the currently running mass-spectrometric facility in the Vernadsky Institute of Geochemistry and Analytical Chemistry in Moscow, Russia, in order to obtain additional reliable evidence for CFF-Xe and to enable the in-depth investigation of its origin. It will also study carefully the source of excess 129Xe in MORB basalt, CO2 gases, samples from deep drilling wells, ancient rocks and meteorites, in order to understand the role that CFF-Xe played in the present-day Xe composition. Finally, it will revise concepts on the evolution of the terrestrial atmosphere on the basis of the presence of CFF-Xe.

The following results are expected: the formation mechanism of CFF-Xe will be revealed by specially designed laboratory experiments; new data on the presence of CFF-Xe in various natural materials will be obtained; and the role of CFF-Xe in isotope geochemistry will be determined.

129Xe in samples already studied will be reconsidered in the light of CFF-Xe. Results will be reported at a number of international conferences on terrestrial geology and planetary sciences, and published in international science journals.

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Coordinatore

Max-Planck Gesellschaft zur Förderung der Wissenschaften e.V.
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Indirizzo
Sanplereheck weg 1
69029 Heidelberg
Germania

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Partecipanti (3)