Objectif The aim of this project lies in the preparation, characterization and study of the catalytic properties of zeolites and activated carbons with immobilized and anchored first-row late transition metal complexes with polydentate ligands containing several co-ordination spheres, obtained by Schiff condensation of aldehydes and B-diketones with diamines. Initially, ter and tetradentate ligands with co-ordination spheres N4, N202, N2S2 will be characterized by spectroscopic (UV-Vis-NIR, Raman, FTIR, EPR, NMR) and electrochemical techniques. The homogeneous catalytic properties of the complexes will also be evaluated.The heterogenization of homogeneous catalysts will be made on two different supporting surfaces: Y-zeolites and activated carbons or carbon molecular sieves. The resulting materials will be characterized by magnetic methods (EPR and NMR), optical (Raman and infrared spectroscopy), microscopic (TEM, STM, AFM), and thermal methods (DSC, TG and TPD/TPR methods). The catalytic properties of the new materials will be evaluated in oxidation/reduction of organic molecules and in the activation of small molecules (CO, CO2, CH4, N2, NO). Programme(s) IC-INTAS - International Association for the promotion of cooperation with scientists from the independent states of the former Soviet Union (INTAS), 1993- Thème(s) 35 - Catalysis and Kinetics Appel à propositions Data not available Régime de financement Data not available Coordinateur Universidade do Porto Contribution de l’UE Aucune donnée Adresse Rua dos Bragas 4099 Porto Portugal Voir sur la carte Coût total Aucune donnée Participants (2) Trier par ordre alphabétique Trier par contribution de l’UE Tout développer Tout réduire Moscow State University M.V. Lomonosov Russie Contribution de l’UE Aucune donnée Adresse 109518 Moscow Voir sur la carte Coût total Aucune donnée Universidade do Porto Portugal Contribution de l’UE Aucune donnée Adresse 4400 Porto Voir sur la carte Coût total Aucune donnée