Cel The main goal of the project is the design of novel homogeneous catalysts on the basis of tailor-made hybrid phosphine ligands.In the course of the project a number of functional hybrid phosphines will be obtained from a wide range of primary phosphines, based on the reactions of primary phosphines with functionalised halides or aldehydes in the presence of functionalised amines, especially amino acids. The two mutually connected aspects of functional hybrid phosphines, namely, water-solubility and binucleating ability towards hard and soft transition metals, due to the hydrophilic properties and reactivity of the functional groups, will be investigated, with the major goal of designing highly effective and stereoselective catalysts for mono- and biphasic reactions, such as olefin metathesis, polymerisation of e-caprolactone, ethylene carbonate, and glycolide; and co-polymerisation of e-caprolactone, ethylene carbonate, or olefins with carbon monoxide; and chiral polymerisation of L-(-)-lactide, leading towards biodegradable polymers.Therefore a sophisticated investigation of the properties of the desired novel phosphines is proposed, uniting the efforts of organoelement, organometallic, structural, and catalytic teams. This approach provides the possibility of solving a number of fundamental problems, such as reactivity of hybrid phosphines, structure and behaviour of their transition metal complexes in solution, mechanism and structure of intermediates of the catalytic processes, as well as a number of applied problems of precatalyst design, the most effective conditions for the catalytic reactions, as well as utilisation of the results in industry. Program(-y) IC-INTAS - International Association for the promotion of cooperation with scientists from the independent states of the former Soviet Union (INTAS), 1993- Temat(-y) 3 - Chemistry OPEN - OPEN Call Zaproszenie do składania wniosków Data not available System finansowania Data not available Koordynator Universität Leipzig Wkład UE Brak danych Adres Johannisallee 29 04103 Leipzig Niemcy Zobacz na mapie Koszt całkowity Brak danych Uczestnicy (5) Sortuj alfabetycznie Sortuj według wkładu UE Rozwiń wszystko Zwiń wszystko A. E. Arbusov Institute of Organic and Physical Chemistry Rosja Wkład UE Brak danych Adres Arbusov str. 8 420088 Kazan Zobacz na mapie Koszt całkowity Brak danych Russian Academy of Sciences Rosja Wkład UE Brak danych Adres Tropinina ultica, 49 603600 Nizhny Novgorod Zobacz na mapie Koszt całkowity Brak danych Russian Academy of Sciences Rosja Wkład UE Brak danych Adres Institutsky Prospect 142432 Chernogolovka, Moscow district Zobacz na mapie Koszt całkowity Brak danych TECHNION - ISRAEL INSTITUTE OF TECHNOLOGY Izrael Wkład UE Brak danych Adres Technion City HAIFA Zobacz na mapie Koszt całkowity Brak danych University of Wales, Bangor Zjednoczone Królestwo Wkład UE Brak danych Adres Deniol Road LL57 2UW Bangor Zobacz na mapie Koszt całkowity Brak danych