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Contenuto archiviato il 2022-12-23

Deterministic and stochastic dynamics of electron transfer in quasi-molecular systems

Obiettivo

The project addresses a fundamental issue of the physics of collisional processes involving charged particles, and proposes both a novel approach to interpret the dynamics on a stochastic basis, and experiments aimed at verifying the validity of the approach for a wide range of conditions. In particular, the project aims at providing a detailed understanding of electron transfer phenomena in temporary quasi-molecular systems formed in collisional events. Traditional quantum mechanical description of such systems often fails due to the complexity of calculations. The difficulties will be overcome by complementing the traditional methods by a newly developed approach, the stochastic ionisation model. This alternative approach treats the process as escape of weakly bound electron during the collision in the form of a stochastic migration along overlapping multiple ionisation channels.
The basis of this novel approach has already been set thanks to the previous collaborative efforts by two of the participating teams. The project proposes to extend the approach to more complicated systems and more realistic conditions. A distinctive feature of the project is a close collaboration between theory and experiment. To this aim, up-to-date experiments will be specifically designed and carried out to verify and assess the validity of the stochastic ionisation approach. In particular, due to the increased collision times, low temperature Rydberg atom systems are ideally suited to observe dramatic modifications of the collisional ionisation behaviour. Experiments using laser-cooling and trapping technologies will be undertaken to demonstrate such effects.
The project promises original and timely contributions to the detailed understanding of the collisional behaviour in the emerging, and still largely unexplored, field of low, and ultra-low temperature systems. The expected outcomes will be relevant role for predicting and controlling electron transfer in complex experimental situations. Furthermore, applications of the results can be envisioned in a large array of disciplines, ranging from astrophysical plasmas to isotope separation and applications in environmental monitoring, biophysics and chemical reaction control.
The seven teams, belonging to three different INTAS countries (IT, DE, DK) and four different institutes located in Russia, share a high-level expertise and knowledge in the scientific area of the project. Collaborative links between different teams already exist, and they will be further developed within the project, through a management oriented towards a continuous and efficient collaboration and exchange of information. Up-to-date set-ups are available, which require little, or none, additional investments to be suitable for the complex tasks. Funding by INTAS will make possible an optimal and co-ordinated exploitation of the resources available in seven different laboratories towards the achievement of the scientific aims.
The project is broken into three main tasks and a total of seven sub-tasks, each one oriented towards specific experimental implementations, involving collisions of Rydberg alkali atoms with atoms and molecules in thermal and supersonic beam conditions, electron detachment in low energy collisions of hydrogen negative ions, and experiments at ultra-low temperature in magneto-optical traps for neutral alkalis and group II elements. Eleven milestones are defined, for total project duration of 36 months. Original results are expected as outcomes of the project, which will be disseminated through publications in international journals and participation in international conferences. Furthermore, a web page devoted to the project will be maintained in order to ensure a timely and broad dissemination of the main results achieved.

Invito a presentare proposte

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Meccanismo di finanziamento

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Coordinatore

Dipartimento di Fisica
Contributo UE
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Indirizzo
Via Filippo Buonarroti 2
56127 Pisa
Italia

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Costo totale
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Partecipanti (6)