Cel The primary scientific objectives of this project are twofold, 1) to develop a methodology to access novel enantiomerically pure chiral C3 symmetric tricyclic monophosphines and, 2) to verify their utility as chiral ligands in transition metal catalysed asymmetric reactions. This project will involve both organic and organometallic chemistry. Organic chemistry will be used for the preparation of these novel C3 symmetric tricyclic monophosphines using known methodologies such as the ring-closing-metathesis reaction, 1,4 addition reactions and the Heck reaction. Organometallic chemistry will be used for the synthesis, isolation, purification and characterisation of novel chiral transition metal catalysts based on these phosphines. The chemical and physico-chemical characteristics of these catalysts will be studied and these catalysts will be tested in asymmetric transformations. In particular, attention will be turned toward palladium-catalysed asymmetric allylic alkylation reactions, palladium-catalysed asymmetric hydrosilylation of alkenes with trichlorosilane and ruthenium-catalysed asymmetric ring-closing-metathesis reactions. Dziedzina nauki natural scienceschemical sciencesorganic chemistryorganic reactionsnatural scienceschemical sciencesinorganic chemistryorganometallic chemistrynatural scienceschemical sciencescatalysis Słowa kluczowe Catalysis Organic Chemistry Organometallic Chemistry Physical sciences Program(-y) FP7-PEOPLE - Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013) Temat(-y) PEOPLE-2007-2-1.IEF - Marie Curie Action: "Intra-European Fellowships for Career Development" Zaproszenie do składania wniosków FP7-PEOPLE-2007-2-1-IEF Zobacz inne projekty w ramach tego zaproszenia System finansowania MC-IEF - Intra-European Fellowships (IEF) Koordynator FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA Wkład UE € 151 369,07 Adres AVENIDA PAISSOS CATALANS 16 43007 Tarragona Hiszpania Zobacz na mapie Region Este Cataluña Tarragona Rodzaj działalności Research Organisations Kontakt administracyjny Ana Margarita Segura Hoogendam (Dr.) Linki Kontakt z organizacją Opens in new window Strona internetowa Opens in new window Koszt całkowity Brak danych