Obiettivo Hierarchically organised metal organic catalysts shall be developed which can be easily recycled in multi-batch processes or which can be used in continuous processes without loosing the original advantages of the corresponding homogeneous soluble metal organic catalysts - high selectivity, activity and stability. The catalysts will be constructed using components at the nano-scale in a bottom-up approach. Hereby, catalytically active metal complexes will be linked with nanoparticles such as polymeric microgels, hyperbranched polymers or hybrid systems consisting of silsesquioxanes attached to hyperbranched polymers. Further hierarchical organisation of HiCat catalysts will be accomplished by interconnected networks formed from the assemblies of catalytic nanoparticles using end-functional T-responsive polymers that can interact with functionalities on the surface of the nanoparticles as binding agents. Recycling of the catalyst-nanoparticle entities in multi-batch operation will be studied utilizing the change of solubility of the polymer supported catalysts by external stimuli. Based on polymer-nanoparticles linked by T-responsive polymers, new types of films and membranes with graded porosity can be prepared by varying the size of the nanoparticles and the length of T-sensitive polymers. This opens new opportunities for integration of catalytic steps and separation within the hierarchically structured system and, hence for continuous reactor operation. The proposal combines the superiority of homogeneous metal-organic catalysts often possessing nearly 100 % selectivity with the advantage of efficient separation by grabbing a new concept for building up hierarchically organised catalytic systems. Structural principles of tailor-made ligands will be transferred into tailor-made functional surfaces of nanoparticles. For proof of principle of the concept, three types of reactions will be studied: olefin metathesis, CX coupling and enantioselective hydrogenation. Campo scientifico engineering and technologyenvironmental engineeringwaste managementwaste treatment processesrecyclingnatural scienceschemical sciencespolymer sciencesnatural scienceschemical sciencescatalysisengineering and technologynanotechnologynano-materials Parole chiave enatioselective hydrogenation hydroformylation hyperbranched polymers metal-organic catalysts nanoparticles olefin metathesis polymer microgels silsesquioxanes Programma(i) FP7-NMP - Specific Programme "Cooperation": Nanosciences, Nanotechnologies, Materials and new Production Technologies Argomento(i) NMP-2007-2.4-2 - Nanostructured catalysts with tailor-made functional surfaces Invito a presentare proposte FP7-NMP-2007-SMALL-1 Vedi altri progetti per questo bando Meccanismo di finanziamento CP-FP - Small or medium-scale focused research project Coordinatore EVONIK INDUSTRIES AG Contributo UE € 654 386,00 Indirizzo RELLINGHAUSER STRASSE 1-11 45128 Essen Germania Mostra sulla mappa Regione Nordrhein-Westfalen Düsseldorf Essen, Kreisfreie Stadt Contatto amministrativo Juergen Czwalinna (Dr.) Collegamenti Contatta l’organizzazione Opens in new window Sito web Opens in new window Costo totale Nessun dato Partecipanti (8) Classifica in ordine alfabetico Classifica per Contributo UE Espandi tutto Riduci tutto TECHNISCHE UNIVERSITEIT EINDHOVEN Paesi Bassi Contributo UE € 352 066,00 Indirizzo GROENE LOPER 3 5612 AE Eindhoven Mostra sulla mappa Regione Zuid-Nederland Noord-Brabant Zuidoost-Noord-Brabant Tipo di attività Higher or Secondary Education Establishments Contatto amministrativo Paul (P.M.L.O.) Scholte (Dr.) Collegamenti Contatta l’organizzazione Opens in new window Sito web Opens in new window Costo totale Nessun dato HYBRID CATALYSIS BV Paesi Bassi Contributo UE € 225 600,00 Indirizzo DEN DOLECH 2 5612 AZ Eindhoven Mostra sulla mappa Regione Zuid-Nederland Noord-Brabant Zuidoost-Noord-Brabant Tipo di attività Private for-profit entities (excluding Higher or Secondary Education Establishments) Contatto amministrativo Hendrikus C.L. Abbenhuis (Dr.) Collegamenti Contatta l’organizzazione Opens in new window Sito web Opens in new window Costo totale Nessun dato IDRYMA TECHNOLOGIAS KAI EREVNAS Grecia Contributo UE € 395 390,00 Indirizzo N PLASTIRA STR 100 70013 Irakleio Mostra sulla mappa Regione Νησιά Αιγαίου Κρήτη Ηράκλειο Tipo di attività Research Organisations Contatto amministrativo Zinovia Papatheodorou (Ms.) Collegamenti Contatta l’organizzazione Opens in new window Sito web Opens in new window Costo totale Nessun dato INSTITUTE OF ORGANIC CHEMISTRY - POLISH ACADEMY OF SCIENCES Polonia Contributo UE € 343 176,00 Indirizzo ul. Kasprzaka 44/52 01-224 Warszawa Mostra sulla mappa Regione Makroregion województwo mazowieckie Warszawski stołeczny Miasto Warszawa Tipo di attività Research Organisations Contatto amministrativo Karol Grela (Dr.) Collegamenti Contatta l’organizzazione Opens in new window Sito web Opens in new window Costo totale Nessun dato IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE Regno Unito Contributo UE € 297 718,00 Indirizzo SOUTH KENSINGTON CAMPUS EXHIBITION ROAD SW7 2AZ LONDON Mostra sulla mappa Regione London Inner London — West Westminster Tipo di attività Higher or Secondary Education Establishments Contatto amministrativo Shaun Power (Mr.) Collegamenti Contatta l’organizzazione Opens in new window Sito web Opens in new window Costo totale Nessun dato EVONIK MEMBRANE EXTRACTION TECHNOLOGY LIMITED Regno Unito Contributo UE € 215 845,00 Indirizzo CHIPPENHAM DRIVE TEGO HOUSE MK10 0AF MILTON KEYNES Mostra sulla mappa Tipo di attività Private for-profit entities (excluding Higher or Secondary Education Establishments) Contatto amministrativo Andrew Timothy Boam (Dr.) Collegamenti Contatta l’organizzazione Opens in new window Sito web Opens in new window Costo totale Nessun dato UNIVERSIDAD NACIONAL DE EDUCACION A DISTANCIA Spagna Contributo UE € 163 036,00 Indirizzo CALLE BRAVO MURILLO 38 PLANTA 7 28015 Madrid Mostra sulla mappa Regione Comunidad de Madrid Comunidad de Madrid Madrid Tipo di attività Higher or Secondary Education Establishments Contatto amministrativo Paloma Centeno (Ms.) Collegamenti Contatta l’organizzazione Opens in new window Sito web Opens in new window Costo totale Nessun dato EVONIK OPERATIONS GMBH Partecipazione conclusa Germania Contributo UE Nessun dato Indirizzo RELLINGHAUSER STRASSE 1-11 45128 Essen Mostra sulla mappa Regione Nordrhein-Westfalen Düsseldorf Essen, Kreisfreie Stadt Tipo di attività Private for-profit entities (excluding Higher or Secondary Education Establishments) Contatto amministrativo Juergen Czwalinna (Dr.) Collegamenti Contatta l’organizzazione Opens in new window Costo totale Nessun dato