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Content archived on 2024-06-18

Catalytic C-H activation-Initiated Tandem Reactions: Devise, Study and Application to natural renewable molecules

Objective

On the one hand, it is now assumed that in the near future the starting materials in chemistry have to come from renewable feedstock and not only from petroleum cracking. On the other hand, the stability of the chemical bonds in saturated hydrocarbons makes them generally unreactive, and a large variety of hydrocarbons constitute a large lowcost feedstock misused, which is treated as fuel or waste. But the invention of processes in which carbon–hydrogen (C–H) bonds in hydrocarbons can be activated is allowing chemists to exploit organic compounds in previously unimaginable ways. The reactions initiated by C-H activation could revolutionize the chemical industry and is nowadays a reality. The impressive potential of catalytic C-H activation reactions represents a new milestone in organic synthesis. An approach to treat the first issue described would be to “C-H activate” natural renewable molecules (simple molecules obtained easily from, for example, oil from plants) and employ them as starting materials for fine chemistry. The global objective of this project is to learn the last top advances in catalytic C-H activation and apply them to the transformation of natural renewable molecules. The specific aims of my research project are: 1) Devising C-H activation-initiated tandem reactions with Rhodium catalysts and explore its application to organic synthesis. 2) Transfer the developed methodology to the transformation of some natural renewable products – in particular Oleic Acid – into valuable molecules like drugs or drug-precursors. 3) Initiate the development of new catalysts for C-H activation-initiated tandem reactions based on group 10 metals

Fields of science (EuroSciVoc)

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Keywords

Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)

Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

FP7-PEOPLE-IOF-2008
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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MC-IOF - International Outgoing Fellowships (IOF)

Coordinator

AGENCIA ESTATAL CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS
EU contribution
€ 229 077,83
Address
CALLE SERRANO 117
28006 MADRID
Spain

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Region
Comunidad de Madrid Comunidad de Madrid Madrid
Activity type
Research Organisations
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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