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Content archived on 2024-06-18

New pincer-type complexes derived from 2-indenylidene ligands

Objective

The group of D. Bourissou has recently reported a new family of indenyl-type ligands bearing one or two coordinating side-arms. These new ligands have allowed the preparation of several metal complexes (Zr, Rh, Pd) exhibiting original coordination modes: eta-1 indenyl and 2-indenylidene. In this project, we envision to take advantage of the strong sigma-donor character of such original 2-indenylidene pincer ligands (i) to stabilise oxo and peroxo complexes of late transition metals and (ii) to explore their activity in hydroamination reactions.

Call for proposal

FP7-PEOPLE-2009-IEF
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Coordinator

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
EU contribution
€ 165 645,60
Address
RUE MICHEL ANGE 3
75794 Paris
France

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Region
Ile-de-France Ile-de-France Hauts-de-Seine
Activity type
Research Organisations
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