Objective
The aim of this project is the synthesis and structural characterization of nitroso derivatives of the heavier group IV elements, R3E-NO (E = Si, Ge, Sn). The substituents R are varied in size, electronegativity and molecular hardness in order to study these effects on the bonding situation around the central atom. Besides the synthesis a major part of the project should involve the structural characterization by gas phase electron diffraction, which seems to be the method of choice for this new class of molecules. However, it is also intended to explore the further chemistry of these compounds. In particular, reactions with compounds bearing Pi-systems like alkenes, disilenes, iminosilanes etc. seem to be promising regarding the build-up of new (ring) systems. After isolation and structural characterization of the nitroso compounds, CVD related applications will be the focus of the work. Especially the synthesis of new Si-N-O and Si-O-N-C based materials seems to be an exciting topic of research. Nevertheless, even for CVD related processes the knowledge about the gas-phase structure of nitroso compounds is essential for a prediction of the properties of the synthesized materials.
Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
FP7-PEOPLE-2009-IEF
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Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
33615 BIELEFELD
Germany
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.