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Content archived on 2024-06-18

Functional Nanoscale Coordination Polymers: Controlled Growth by Metal-Containing Block Copolymer Templated Self-Assembly

Objective

Coordination polymers are infinite arrays of bridging ligands bound to two or more transition metal ions. The potential application of coordination polymers in the areas of materials and nanoscience is significant as their properties can be tuned through variation of the transition metal ions and bridging ligands. To date, research in the area of functional nanoscale coordination polymers has been limited to amorphous (spherical) and crystalline (non-spherical) examples and the controlled growth of coordination polymers has not been realized. We propose the use of metal-containing diblock copolymer templates, which self-assemble in a number of different morphologies depending on the volume fraction of the blocks, to influence the structure of coordination polymers on the nanoscale, and for the first time demonstrate control over their size and shape. Our approaches will afford multifunctional materials with highly tunable properties, and the incorporation of diblock copolymers will allow for the rational design and controlled growth of nanoscale coordination polymers. This highly interdisciplinary and multidisciplinary research proposal requires a wide range of skills and this is exactly the mix possessed by the applicant (ligand design, coordination chemistry, stable-radical chemistry, electrochemistry, and molecule-based magnetism) and the host laboratory (polymer chemistry, materials chemistry, and nanoscience). The proposed research will bring a promising young researcher to Europe, and will lead to a new area of functional polymer and materials research where a range of potential applications are envisioned.

Fields of science (EuroSciVoc)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

FP7-PEOPLE-2009-IIF
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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MC-IIF - International Incoming Fellowships (IIF)

Coordinator

UNIVERSITY OF BRISTOL
EU contribution
€ 173 240,80
Address
BEACON HOUSE QUEENS ROAD
BS8 1QU Bristol
United Kingdom

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Region
South West (England) Gloucestershire, Wiltshire and Bristol/Bath area Bristol, City of
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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