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Abstract

The behaviour of solid polymer electrolytes based on POE and a lithium salt are strongly dependant on the processes of recrystallisation of the polymer chains. These can be reduced by the use of a blend comprising high molecular mass POE, an elastomer and a macromonomer of POE. The impedance analysis of these new solid electrolytes shows that the ionic conductivity, and also the interface transport, are governed by the content of the amorphous phase in the electrolyte environment, which can be modified by the proportion of macromonomer. Moreover, the conductivity follows an Arrhenius-type law rather than one of free volume, because of the reduced mobility of the polymer chains.

Additional information

Authors: HAMAIDE T, CNRS, Laboratoire des Materiaux Organiques, Lyon-Vernaison (FR);CARRE C, CNRS, Laboratoire des Materiaux Organiques, Lyon-Vernaison (FR);GUYOT A, CNRS, Laboratoire des Materiaux Organiques, Lyon-Vernaison (FR)
Bibliographic Reference: Paper presented: JEPO, Chantilly (FR) Oct 17-21 1988
Availability: Available from (1) as Paper FR 34240 ORA
Record Number: 198910238 / Last updated on: 1994-12-01
Category: PUBLICATION
Original language: fr
Available languages: fr