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Abstract

M-r=737.1, monoclinic, P2-1/c, a=9.260(3), b=15.997(4), c=14.756(3) Angstroem, beta=108.22(2)SOD, V = 2076(2) Angstroem**3, Z = 4, D-x = 2.358 g cm**-3, LAMBDA(Mo Kalpha)=0.71073 ANGSTROEM, mu=130.960 cm**-1, F(000)=1352, T=295(1)K, R=0.033 for 1969 observed reflections. The title compound is isostructural with its chlorine analogue. Coordination about the U atom is pseudo-octahedral with one eta**5-C-9H-7 ligand and one coordinated C-4H-8O molecule occupying transaxial positions. A second C-4H-8O molecule and three Br atoms occupy equatorial positions. The results and conclusions reported for (U(C-9H-7))Cl-3.2C-4H-8O are entirely corroborated by the present structure analysis.

Additional information

Authors: REBIZANT J, JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART-TILMAN (BELGIUM);SPIRLET M R, JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART-TILMAN (BELGIUM);GOFFART J JRC KARLSRUHE ESTAB. (GERMANY), JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART-TILMAN (BELGIUM);UNIVERSITE DE LIEGE AU SART-TILMAN (BELGIUM), JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART-TILMAN (BELGIUM)
Bibliographic Reference: ACTA CRYSTALLOGRAPHICA, VOL. C41 (1985), PP. 334-336
Record Number: 1989123098900 / Last updated on: 1987-01-01
Category: PUBLICATION
Available languages: en