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  • STRUCTURAL INVESTIGATIONS OF THE ISOMORPHOUS PROPIONITRILE TRIS (N5-CYCLOPENTADIENYL) LANTHANOID (III) (LN = LA, PR, YB) COMPLEXES AND OF THE CORRESPONDING 1 - 2 ADDUCTS

Abstract

1:1 adducts (C5H5)3Ln(NCCH2CH3) (Ln=La, Pr, Yb), of the strongly Lewis acidic organolanthanoid complexes (C5H5)3Ln with the aliphatic nitrile CH2CH3CN have been prepared and characterised by threedimensional Xray diffraction data. Their crystal and molecular structures are presented here. The crystal structure of the 1:2 adduct, (C5H5)3La(NCCH2CH3)2 has also been investigated and is compared with that of the 1:1 adducts.

Additional information

Authors: SPIRLET M R, UNIVERSITE DE LIEGE AU SART TILMAN (BELGIUM);JRC + KARLSRUHE ESTAB. (GERMANY);KERFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);REBIZANT J, UNIVERSITE DE LIEGE AU SART TILMAN (BELGIUM);JRC + KARLSRUHE ESTAB. (GERMANY);KERFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);APOSTOLIDIS C, UNIVERSITE DE LIEGE AU SART TILMAN (BELGIUM);JRC + KARLSRUHE ESTAB. (GERMANY);KERFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);KANELLAKOPULOS B UNIVERSITE DE LIEGE AU SART TILMAN (BELGIUM), UNIVERSITE DE LIEGE AU SART TILMAN (BELGIUM);JRC + KARLSRUHE ESTAB. (GERMANY);KERFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);JRC + KARLSRUHE ESTAB. (GERMANY), UNIVERSITE DE LIEGE AU SART TILMAN (BELGIUM);JRC + KARLSRUHE ESTAB. (GERMANY);KERFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);KERFORSCHUNGSZENTRUM KARLSRUHE (GERMANY), UNIVERSITE DE LIEGE AU SART TILMAN (BELGIUM);JRC + KARLSRUHE ESTAB. (GERMANY);KERFORSCHUNGSZENTRUM KARLSRUHE (GERMANY)
Bibliographic Reference: 2ND INTERNATIIONAL CONFERENCE ON THE BASIC AND APPLIED CHEMISTRY OF F-TRANSITION (LANTHANIDES AND ACTINIDES) AND RELATED ELEMENTS LISBOA (PORTUGAL), APRIL 6-10, 1987 WRITE TO CEC LUXEMBOURG, DG XIII/A2, POB 1907 MENTIONING PAPER E 33499 ORA
Availability: Can be ordered online
Record Number: 1989126007800 / Last updated on: 1988-02-01
Category: PUBLICATION
Available languages: en