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Abstract

Reaction of UCp3C1 (Cp = cyclopentadienyl) with ThC14 in acetonitrile led to the obtention of the title complex as characterised by xray diffraction. This salt provides a new example of the (UCp3(NCCH3)2)f5 cationic species of trigonal bipyramidal coordination and contains simultaneously as anion the first example of an AnX4.2L (An = actinides. X = C1 or Br) type complex with a cyclopentadienyl ring as donor ligand. In the anion the coordination of geometry about the thorium atom is distorted octahedral.

Additional information

Authors: REBIZANT J, JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART TILMAN (BELGIQUE);KERNFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);APOSTOLIDIS C, JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART TILMAN (BELGIQUE);KERNFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);SPIRLET M R, JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART TILMAN (BELGIQUE);KERNFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);KANELLAKOPULOS B JRC KARLSRUHE ESTAB. (GERMANY), JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART TILMAN (BELGIQUE);KERNFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);UNIVERSITE DE LIEGE AU SART TILMAN (BELGIQUE), JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART TILMAN (BELGIQUE);KERNFORSCHUNGSZENTRUM KARLSRUHE (GERMANY);KERNFORSCHUNGSZENTRUM KARLSRUHE (GERMANY), JRC KARLSRUHE ESTAB. (GERMANY);UNIVERSITE DE LIEGE AU SART TILMAN (BELGIQUE);KERNFORSCHUNGSZENTRUM KARLSRUHE (GERMANY)
Bibliographic Reference: 2ND INTERNATIONAL CONFERENCE ON THE BASIC AND APPLIED CHEMISTRY OF F-TRANSITION (LANTHANIDES AND ACTINIDES) AND RELATED ELEMENTS, LISBOA (PORTUGAL), APRIL 6-10, 1987 WRITE TO CEC LUXEMBOURG, DG XIII/A2, POB 1907 MENTIONING PAPER E 33500 ORA
Availability: Can be ordered online
Record Number: 1989126008000 / Last updated on: 1988-02-01
Category: PUBLICATION
Available languages: en
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