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Abstract

The occupied and unoccupied electronic states of NaO-2 and KO-2 have been investigated by UV photoemission spectroscopy and inverse photoemission spectroscopy, respectively. In addition single electron excitations from occupied into empty levels have been probed by X-ray absorption and electron energy loss spectroscopy. The experimental data are augmented by LCGTO-"sl X/"alpha model cluster calculations. A detailed assignment of initial and final states is given. The excitation cross sections and an inversion of the ligand field induced 3"it d/" level splitting in NaO-2 are discussed.

Additional information

Authors: BERTEL E, MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);MEMMEL N, MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);JACOB W, MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);DOSE V, MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);NETZER F P, MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);ROSINA G, MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);RANGELOV G, MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);ASTL G, MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);ROESCH N MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY), MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA), MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY);TU MUENCHEN, GARCHING (GERMANY), MAX-PLANCK-INSTITUT FUER PLASMAPHYSIK, GARCHING (GERMANY);INST. FUER PHYSIKALISCHE CHEMIE, UNIV. INNSBRUCK (AUSTRIA);TU MUENCHEN, GARCHING (GERMANY)
Bibliographic Reference: APPLIED PHYSICS A, VOL. 47 (1988) PP. 87-89
Record Number: 1989126114300 / Last updated on: 1989-06-01
Category: PUBLICATION
Available languages: en
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