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The crystal structure of Tris(eta 5-cyclopentadienyl) phenolatouranium (IV) is reported. The three cyclo-penta-dienyl rings are eta5-covalently bonded to uranium to form a distorted tetrahedron with the oxygen of the phenoxide. The most important feature is the presence of the OXO functional group with a U-O distance of 2.119 Angstrom and a U-O-C (16) angle of 159.4 .

Additional information

Authors: SPIRLET M R, JRC Karlsruhe (DE);REBIZANT J, JRC Karlsruhe (DE);APOSTOLIDIS C, JRC Karlsruhe (DE);VAN DEN BOSSCHE G, Université de Liège au Sart Tilman, Cristallographie B5, Liège (BE);KANELLAKOPULOS B, Institut für Heisse Chemie, Kernforschungszentrum Karlsruhe GmbH, Karlsruhe (DE)
Bibliographic Reference: Article: Acta Crystallographica, Vol. C46 (1990) pp. 2318-2320
Record Number: 199110638 / Last updated on: 1994-12-02
Original language: en
Available languages: en