Community Research and Development Information Service - CORDIS

Abstract

Acetate ions can function as both monodentate and bidentate ligands but the crystallochemical factors which favour one of these two coordinations are not known. The title compound is a product obtained while attempting to synthesise tris(cyclopentadienyl)uranium acetate. Within the large series of cyclopentadienyl complexes of uranium(IV), the title compound is the first observed where the uranium(IV) exhibits a coordination number of seven. The bridging between U atoms occurs through acetate and oxide O atoms. The cyclopentadienyl ligands occupy the apical coordination sites of the bipyramids. The characterisation and structure analysis of this compound by single crystal X-ray diffraction are reported.

Additional information

Authors: REBIZANT J, JRC Karlsruhe (DE);SPIRLET M R, JRC Karlsruhe (DE);APOSTOLIDIS C, JRC Karlsruhe (DE);KANELLAKOPULOS B, Kernforschungszentrum Karlsruhe (DE)
Bibliographic Reference: Article: Acta Crystallographica, Vol. C48 (1992) pp. 452-454
Record Number: 199210743 / Last updated on: 1994-12-02
Category: PUBLICATION
Original language: en
Available languages: en
Follow us on: RSS Facebook Twitter YouTube Managed by the EU Publications Office Top