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Abstract

By combining positive and negative chemical ionisation during the same GC/MS analysis it is possible to increase the sensitivity for the low chlorinated PCBs by a factor of 3.5-7 when compared with pure negative ion chemical ionisation. By the use of isobutane as ionisation gas, detection limits down to 100 femtogram per injected micro-l can be reached. Data are presented on the separation of PCB 163 and 138.

Additional information

Authors: BOWADT S, JRC Ispra (IT);LARSEN B R, JRC Ispra (IT);FRANDSEN E, University of Odense, Department of Chemistry (DK);WEIMANN A, University of Odense, Department of Chemistry (DK);MOLLER J, University of Odense, Department of Chemistry (DK)
Bibliographic Reference: Paper presented: 15th International Symposium on Capillary Chromatography, Riva del Garda (IT), May 24-27, 1993
Availability: Available from (1) as Paper EN 37571 ORA
Record Number: 199310890 / Last updated on: 1994-11-29
Category: PUBLICATION
Original language: en
Available languages: en