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The enthalpies of solution of BaCmO(3) and BaCfO(3) were measured. The resulting standard molar enthalpies of formation, together with other corresponding experimental values for several lanthanide, actinide and transition metal complex oxides with barium and strontium, have been used to estimate the molar enthalpies of formation of a number of homologous actinide compounds. The present results also provide additional information on the standard molar enthalpy of formation of CfO(2) and on the Cf(4+)/Cf(3+) standard potential.

Additional information

Authors: FUGER J, JRC Karlsruhe (DE);HAIRE R G, Oak Ridge National Laboratory, Transuranium Research Laboratory (Chemistry Division) (US);PETERSON J R, University of Tennessee, Department of Chemistry, Knoxville (US)
Bibliographic Reference: Article: Journal of Alloys and Compounds, Vol. 200 (1993) pp. 181-185
Record Number: 199311627 / Last updated on: 1994-11-28
Original language: en
Available languages: en