Studies of U(C(5)H(5))(3)Cl : II - Temperature dependence of the molecular configurations
Uranium tris(cyclopentadienyl)chlorine (UCp(3)Cl) exhibits two phase transitions between 300 K and 5 K. This paper discusses the crystallographic structures which show a transition at 245 K from the centrosymmetric space group P2(1)/n at 300 K to the non-centrosymmetric space group Pn observed at 120 K; below 78 K the structure becomes triclinic.
Bibliographic Reference: Article: Molecular Physics
Record Number: 199510048 / Last updated on: 1995-01-10
Original language: en
Available languages: en