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Biphasic Plasmonic Photoelectrocatalytic CO2 Reduction: electrochemically controlling plasmonic photo-charging of metallic nanofilms at immiscible liquid|liquid interfaces towards CO2 reduction

Projektbeschreibung

Neue Methoden für eine drastisch verbesserte Kontrolle bei der CO2-Umwandlung in Brenn- und Kraftstoffe

Das im Rahmen der Marie-Skłodowska-Curie-Maßnahmen finanzierte Projekt CO2PhotoElcat plant die Entwicklung eines revolutionären Ansatzes zur elektrochemischen Reduktion von CO2 auf synthetische Brenn- und Kraftstoffe. Das Projekt wird dafür mehrere Ansätze kombinieren: bahnbrechende Methoden für die Selbstassemblierung von Nanoteilchen in metallische Nanofilme an fluidischen Schnittstellen; Methoden zur Kontrolle des Ionen- und Elektronentransfers an einer nicht mischbaren Flüssig-Flüssig-Grenzfläche; sowie spektroskopische Techniken zur Untersuchung der elektrifizierten Schnittstelle. Die vorgeschlagenen Methoden sollten eine bisher unerreichte elektrochemische Kontrolle der plasmonischen Photoaufladung der metallischen Nanofilme an der Grenzfläche ermöglichen.

Ziel

Conversion of CO2 to synthetic fuels is essential for climate-change mitigation and renewable energy production. This project will develop a novel, disruptive and sustainable approach to the photoelectrocatalytic CO2 reduction reaction (CO2RR). The interdisciplinary methodology will combine breakthrough approaches to self-assemble nanoparticles into metallic nanofilms at fluidic interfaces, with electrochemical control of ion and electron transfer at an immiscible liquid|liquid (L|L) interface, and custom in situ UV/vis and Raman setups to probe the electrified L|L interface. The major innovation will be unprecedented electrochemical-control of the degree of plasmonic photo-charging of the interfacial metallic nanofilms to overcome the kinetic bottleneck of the multielectron, multiproton CO2RR towards more energy-dense C2 or C3 hydrocarbons. This MSCA-IF will significantly support the EU’s goal to decarbonise the energy sector, detailed in the European Green Deal, via high-impact scientific research and intellectual property generation for environmentally-friendly technologies. The Experienced Researcher (ER) will be supervised by Dr Micheál D. Scanlon at the University of Limerick (UL), Ireland, and undertake a secondment with Prof. Steven Bell at Queens University Belfast (QUB), U.K. The ER will engage in well-structured dissemination activities of the project results both to expert scientists and the general public using a multitude of engagement and outreach platforms. While the ER is accomplished in spectroelectrochemistry and nanomaterials synthesis, this fellowship will greatly expand his core scientific experimental and communication skills, international outlook, and broaden his professional network and inter-sectoral employability. Ultimately, this enhanced research capacity will allow the ER is to establish his own world-class research laboratory focusing on electrocatalysis through competitive grant acquisition, e.g. an ERC Starting grant.

Koordinator

UNIVERSITY OF LIMERICK
Netto-EU-Beitrag
€ 184 590,72
Adresse
NATIONAL TECHNOLOGICAL PARK, PLASSEY
- Limerick
Irland

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Region
Ireland Northern and Western Border
Aktivitätstyp
Higher or Secondary Education Establishments
Links
Gesamtkosten
€ 184 590,72