Project description DEENESFRITPL Water’s structure and dynamics under the microscope The microscopic understanding of water concerns the structure and dynamics of the hydrogen-bonding network on which the unique properties of water rely. The ERC-funded WATER project will exploit the innovative X-ray free-electron lasers to investigate the structure and dynamics of water from hot temperatures down to the deeply supercooled regime where the anomalous properties become extreme. The project will experimentally verify certain hypotheses put forward by models. These hypotheses propose the existence of two liquid states of water and a reversible phase transition between these states. Additionally, WATER aims to assess whether these liquids can reach equilibrium at a faster rate than the formation of ice nuclei and provide an explanation for the fluctuations associated with diverging response functions. Show the project objective Hide the project objective Objective We propose to address some of the most important outstanding questions for a microscopic understanding of water: What is the structure and dynamics of the hydrogen-bonding network that give rise to all the unique properties of water? How is the structure and dynamics affected by temperature, pressure and by perturbation through interaction with solutes and interfaces? Here we point to the opportunity to exploit the completely new avenues that the novel x-ray free-electron lasers open up for probing both structure and dynamics of water from hot temperatures down to the deeply supercooled regime where the anomalous properties become extreme. We plan to further develop fast cooling and ultrafast x-ray probing allowing access to below the homogeneous ice nucleation limit, to probe equilibrium dynamics through probe-probe techniques based on x-ray correlation spectroscopy, to access low-energy vibrational mode dynamics through THz pump and x-ray scattering probe and to transfer x-ray spectroscopies into the time domain.We will address one of the currently most debated issues related to a potential liquid-liquid transition and 2nd critical point in liquid water. The goal is to determine experimentally if water, as hypothesized in certain models, can really exist as two liquids, if there is reversible phase transition between the hypothesized liquids, evaluate if these hypothesized liquids can equilibrate on a time scale faster then the rate of ice nucleation and if there exists a critical point that can explain the fluctuations related to the diverging response functions. We will continue to critically investigate our proposed hypothesis that water at ambient temperature encompasses fluctuations around two local structures and that the dominating structure is a strongly distorted hydrogen bonded environment. We will investigate if these concepts can be used to describe the observed perturbations of water structure by solutes and interfaces. Fields of science natural sciencesbiological sciencesbiochemistrybiomoleculesnatural sciencesphysical sciencesastronomyplanetary sciencesplanetsnatural sciencesearth and related environmental sciencesatmospheric sciencesclimatologyclimatic changesnatural sciencesphysical sciencesopticslaser physicsnatural sciencesphysical sciencesopticsspectroscopy Programme(s) H2020-EU.1.1. - EXCELLENT SCIENCE - European Research Council (ERC) Main Programme Topic(s) ERC-ADG-2014 - ERC Advanced Grant Call for proposal ERC-2014-ADG See other projects for this call Funding Scheme ERC-ADG - Advanced Grant Host institution STOCKHOLMS UNIVERSITET Net EU contribution € 2 486 951,00 Address UNIVERSITETSVAGEN 10 10691 Stockholm Sweden See on map Region Östra Sverige Stockholm Stockholms län Activity type Higher or Secondary Education Establishments Links Contact the organisation Opens in new window Website Opens in new window Participation in EU R&I programmes Opens in new window HORIZON collaboration network Opens in new window Total cost € 2 486 951,25 Beneficiaries (1) Sort alphabetically Sort by Net EU contribution Expand all Collapse all STOCKHOLMS UNIVERSITET Sweden Net EU contribution € 2 486 951,00 Address UNIVERSITETSVAGEN 10 10691 Stockholm See on map Region Östra Sverige Stockholm Stockholms län Activity type Higher or Secondary Education Establishments Links Contact the organisation Opens in new window Website Opens in new window Participation in EU R&I programmes Opens in new window HORIZON collaboration network Opens in new window Total cost € 2 486 951,25
