Objective In the current IIF application, the candidate, Oleksii V. Gutov (1984, Ukraine) describes a 2-year postdoctoral project to be carried out in the group of Dr. Alexandr Shafir at the Institute of Chemical Research of Catalonia (ICIQ), a leading European catalysis center in Tarragona, Spain. As a Marie Curie fellow at ICIQ, Dr. Gutov will apply his unique expertise in Metal-Organic Frameworks (MOFs) field to the development of catalysts for the selective ethylene and ethanol upgrade, an area in urgent need of conceptually new catalytic materials, and where any advance could mean an important step towards Europe’s more sustainable (environmentally and economically) future. We aim at creating catalytic processes for selective conversion of low-value two-carbon feedstocks, ethanol and ethylene, into valuable longer-chain substances. State-of-the art examples include the d-metal-catalyzed upgrade of ethanol to 1-butanol, and the tetramerization of ethylene to 1-octene. The selectivity and efficiency in such processes is insufficient. We propose placing the catalyst within the pores/channels of a MOF, thus altering the selectivity via confinement effects. The approach (through varying the MOF structure) would give access to species currently unattainable, such as 1-hexanol (from ethanol) or 1-decene, as well as improve the selectivity/efficiency of the already existing processes. The research proposed requires deep understanding of both MOF materials and catalysis. Having previously gained valuable experience with MOFs with a leader in the field (prof. J. Hupp, Northwestern), the applicant will be uniquely positioned to undertake this cutting-edge investigation at an institution dedicated to catalysis. With notable exceptions, most of MOF research in Europe is centered on basic investigations, gas storage and separation. As a broader objective, adding MOF-based catalyst to this repertoire would help position Europe as a leader in sustainable chemistry and renewable energies Fields of science engineering and technologyenvironmental engineeringenergy and fuelsrenewable energynatural scienceschemical sciencesorganic chemistryalcoholsnatural scienceschemical sciencescatalysisnatural scienceschemical sciencesorganic chemistryaliphatic compounds Programme(s) FP7-PEOPLE - Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013) Topic(s) FP7-PEOPLE-2013-IIF - Marie Curie Action: "International Incoming Fellowships" Call for proposal FP7-PEOPLE-2013-IIF See other projects for this call Funding Scheme MC-IIF - International Incoming Fellowships (IIF) Coordinator FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA EU contribution € 173 370,60 Address AVENIDA PAISSOS CATALANS 16 43007 Tarragona Spain See on map Region Este Cataluña Tarragona Activity type Research Organisations Administrative Contact Noèlia Flores (Ms.) Links Contact the organisation Opens in new window Website Opens in new window Total cost No data
