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Maximizing the EU shale gas potential by minimizing its environmental footprint

Periodic Reporting for period 2 - ShaleXenvironmenT (Maximizing the EU shale gas potential by minimizing its environmental footprint)

Reporting period: 2017-03-01 to 2018-08-31

Shale gas has generated enormous economical benefits in North America. For example, using natural gas instead of coal reduced the US CO2 emissions, the availability of abundant natural gas prompted large investments in new chemical plants, and the US is now exporting natural gas. However, producing and exploiting any natural resource comes with inherent environmental risks.

The objective of ShaleXenvironmenT is to develop a framework to quantify the environmental impact of shale gas exploration and production, with emphasis on Europe.

The society will benefit from the success of this project because an independent assessment of the risks associated with shale gas exploration and production will be provided, because fundamental understanding of a number of phenomena will be achieved, and because state-of-the-art technologies will be improved and new ones potentially introduced. Such innovations could lead to the creation of new jobs in highly technical sectors, and the reduction of environmental impact.
Characterization of rock properties. We obtained rock samples from the Bowland formation in the UK, from other EU formations, and from North America. We demonstrated that understanding the mineral-scale control on permeability in these rocks is essential to calculate realistic estimates of the extent of recoverable gas reserves of many European countries. We undertook novel 3D imaging of the microstructure of the shale samples at multiple scales from micro- to nano-metres. We imaged the pores (where gas would be held), the connection between the pores (which control flow of gas) and the natural fractures present (that enhance gas production). In one innovative experiment, we monitored fracturing and healing of rock samples using the synchrotron. We analysed the geomechanical properties of some European shales: Bowland shales, which are clay—poor, deform in a relatively brittle manner. Other European shales are more ductile. The results suggest a low fracture healing rate of Bowland shale and a good potential for hydraulic fracturing.

Rock-fluid interactions. We quantified the amount of hydrocarbons that can be adsorbed at down-hole temperature and pressure conditions in shale rocks. We calculated transport properties of shale gas in mature kerogen and of a variety of fracturing fluid models in clays. Several important data related to the relative strength of interactions of important compounds such as naturally occurring radioactive materials with clay basal and edge surfaces, and their relative mobility. To validate our understanding, we produced engineered materials that contain micro- and mesoscale pores and we used them to address the pore size effect on fluid behaviour. By studying carbon dioxide and light hydrocarbons we obtained results that support the prospective use of CO2 for enhanced desorption of gas from shales.

Hydraulic fracturing fluids. We developed and characterized ‘green’ formulations, based on polysaccharides and viscoelastic surfactants. All formulations exhibited suitable mechanical and rheological properties as well as good thermal resistance. Rhamnolipids, saponins and sodium citrate were found to significantly modify the rheological properties, even in small amounts; carbon black induces electro-responsiveness, increases viscosity and improves thermal resistance; azorubine, a food dye approved by FDA, imparts light-responsiveness. Moreover, the implementation of magnetic field revealed to be an effective strategy in order to further reduce the scale formation and precipitation.

Fluid transport modelling. We developed a molecular-level understanding of the mechanisms by which fluids transport within rock formations. We integrated this understanding in stochastic models to predict the permeability of shale formations when pore distribution, chemical composition, and fluid content are known. We developed software to describe fluid transport in a rock with existing fractures, and we demonstrated that this software can describe the propagation of a fracture network upon hydraulic fracturing stimulation. The software can also describe the alteration of the stress in the sub-surface, which could be used to reduce the likelihood of induced seismicity.

Risk assessment. We developed modelling tools for assessing the safety hazards of shale gas wells. Models for predicting explosion and jet fire consequences of a well blowout, with a computational flow model simulating transient discharge from a well, have been developed. Computational methodologies to assess the risk of induced seismicity during reservoir stimulations have also been developed. The effectiveness of the well-blowout model in a case study based on realistic design of a shale gas exploration site has been demonstrated. The induced seismicity model was successfully applied to a case study at an Enhanced Geothermal System in Basel, Switzerland.

Reduction of the environmental impact. We applied optimization methods to minimize the amoun
We pushed the limits of experimental characterization of heterogeneous porous materials, and we developed, e.g. tools and workflows for imaging fracture formation, propagation and healing. Instruments have been developed to measure rock properties at high pressure and high temperature conditions, with a variety of applications. We improved our collective understanding of the behaviour of fluids in narrow pores, with possible outcome the improvement of industrial separation and catalysis processes, in addition to enhanced production of shale gas. We developed new software, which has resulted in competitive economic advantage for small and medium enterprises. The project has identified both similarities and differences between the production of conventional and unconventional hydrocarbons, and the connected risks, which is expected to benefit the society at large via the minimization of the environmental impact of hydrocarbons production.
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