Objectif Recent work at the University of Manchester has developed an efficient synthetic method for transition metal free electrophilic borylation of aromatics and heteroaromatics. This approach has recently been extended to the fusion of conjugated materials containing the acceptor moiety benzothiadiazole – a group that is ubiquitous in materials for organic electronics. This functionalization leads to a significant increase in the electron affinity of the materials and a considerable reduction in the band gap, consistent with near-IR emission in organic light emitting diodes (OLEDs), ambipolar organic field effect transistor (OFET) mobility, improved n-type stability and effective light harvesting in organic photovoltaic cells (OPVs). The BORCOM project will use this methodology to deliver novel molecules and polymers that exhibit high electron affinities and small band gaps by functionalization of azole or azine containing acceptors in the conjugated backbone. The performance of the new materials as n-type semiconductors in OFETs, light harvesting and electron acceptors in OPVs and dopants/emitters in OLEDs will be evaluated. Champ scientifique natural scienceschemical sciencesorganic chemistryhydrocarbonsnatural scienceschemical sciencespolymer sciencesnatural sciencesphysical scienceselectromagnetism and electronicssemiconductivitynatural scienceschemical sciencesanalytical chemistrymass spectrometrynatural sciencesphysical sciencesopticsspectroscopy Programme(s) H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions Main Programme H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility Thème(s) MSCA-IF-2014-EF - Marie Skłodowska-Curie Individual Fellowships (IF-EF) Appel à propositions H2020-MSCA-IF-2014 Voir d’autres projets de cet appel Régime de financement MSCA-IF-EF-ST - Standard EF Coordinateur THE UNIVERSITY OF MANCHESTER Contribution nette de l'UE € 195 454,80 Adresse OXFORD ROAD M13 9PL Manchester Royaume-Uni Voir sur la carte Région North West (England) Greater Manchester Manchester Type d’activité Higher or Secondary Education Establishments Liens Contacter l’organisation Opens in new window Site web Opens in new window Participation aux programmes de R&I de l'UE Opens in new window Réseau de collaboration HORIZON Opens in new window Coût total € 195 454,80
