Polynuclear Gold Catalysis

Projektinformationen

GOLDCLUSTER

ID Finanzhilfevereinbarung: 702524

DOI 10.3030/702524

Abgeschlossenes Projekt

EK-Unterschriftsdatum 10 Februar 2016

Startdatum 27 Juni 2016

Enddatum 26 Juni 2018

Finanziert unter

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Gesamtkosten € 158 121,60

EU-Beitrag € 158 121,60

Koordiniert durch

FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA
Spain

Ziel

During the last decade, homogeneous gold catalysis has witnessed rapid growth for C–C bond forming reactions mainly due to the soft carbophilic Lewis acid properties of gold complexes toward C–C triple bonds. Compared to Lewis acids and other transition metals, gold catalysts are very active under mild conditions, can tolerate moisture and oxygen and are compatible with diverse functional groups. Gold catalyzed tandem and multi-component reactions allow the efficient transformation of simple starting materials in complex molecules, which have been used for the synthesis of numerous biologically active targets. GOLDCLUSTER aims at advancing the field of gold chemistry by the development of new superelectrophilic small gold (I) clusters (Au3, Au6 and Au8). These complexes will be used as catalysts in the retro-Büchner reactions of cycloheptatrienes to form in situ gold carbenes, leading to the formation of complex molecules using milder conditions (lower reaction temperature, more efficient catalysts, and better yields). In addition, the new catalysts will also be tested in the catalytic activation of small molecules, such as methane. GOLDCLUSTER will contribute greatly to the advancement of gold chemistry by exploring new directions in the area and providing new tools to further enhance the development of efficient synthetic methods that could be later adapted by the Chemical Industry, making the European economy more competitive and better aligned with the Horizon2020 growth strategy.

Wissenschaftliches Gebiet

• medical and health sciences › basic medicine › pharmacology and pharmacy › pharmaceutical drugs
• natural sciences › chemical sciences › catalysis
• natural sciences › chemical sciences › organic chemistry › aliphatic compounds
• engineering and technology › environmental engineering › energy and fuels

Programm/Programme

• H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions Main Programme
• H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility

Thema/Themen

• MSCA-IF-2015-EF - Marie Skłodowska-Curie Individual Fellowships (IF-EF)

Aufforderung zur Vorschlagseinreichung

H2020-MSCA-IF-2015

Finanzierungsplan

MSCA-IF-EF-ST - Standard EF

Koordinator

FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA

• Netto-EU-Beitrag: € 158 121,60
• Adresse: AVENIDA PAISSOS CATALANS 16 ; 43007 Tarragona ; Spanien
• Region: Este › Cataluña › Tarragona
• Aktivitätstyp: Research Organisations
• Gesamtkosten: € 158 121,60