Objectif Chirality of organic molecules plays a paramount role in our society as a consequence of the direct relation between the absolute molecular configuration and many properties and applications of molecular compounds and materials. The demand of enantiomerically pure compounds has increased considerably driven by the request of the pharmaceutical industry, as well as applications such as flavours, fragrances, and materials. In this context, the development of new methodologies to obtain enantiomerically pure compounds has become a challenge for the scientific community. This project entitled “Homogeneous and heterogeneous enantioselective Single Electron Transfer (SET) catalysis in cross-coupling reactions (EnanSET)” aims at developing novel enantioselective SET cross-coupling reactions of redox active esters (RAEs) by Ni-complex due to this kind of compounds do not need previous activation. Moreover, in order to develop more environmentally friendly processes, the methodology will be extended to non-toxic SET complex as titanium complexes, with the goal of developing the first Ti-catalysis of RAEs. Additionally, inspired by demand of the industrial processes, the need to develop clean and green chemical processes in order to avoid environmental concerns and the advantages that heterogeneous catalysis provides, we will develop the first SET heterogeneous catalysis with MOFs through the postsynthetic incorporation of chiral Ni or Ti-residues on the pore structure. Champ scientifique natural scienceschemical sciencesinorganic chemistrytransition metalsnatural scienceschemical sciencescatalysis Mots‑clés Single electron transfer enantioselective catalysis MOFs Programme(s) H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions Main Programme H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility Thème(s) MSCA-IF-2016 - Individual Fellowships Appel à propositions H2020-MSCA-IF-2016 Voir d’autres projets de cet appel Régime de financement MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF) Coordinateur UNIVERSIDAD DE GRANADA Contribution nette de l'UE € 239 191,20 Adresse CUESTA DEL HOSPICIO SN 18071 Granada Espagne Voir sur la carte Région Sur Andalucía Granada Type d’activité Higher or Secondary Education Establishments Liens Contacter l’organisation Opens in new window Site web Opens in new window Participation aux programmes de R&I de l'UE Opens in new window Réseau de collaboration HORIZON Opens in new window Coût total € 239 191,20 Partenaires (1) Trier par ordre alphabétique Trier par contribution nette de l'UE Tout développer Tout réduire Partenaire Les organisations partenaires contribuent à la mise en œuvre de l’action, mais ne signent pas la convention de subvention. THE SCRIPPS RESEARCH INSTITUTE CORPORATION États-Unis Contribution nette de l'UE € 0,00 Adresse NORTH TORREY PINES ROAD 10550 92037 1000 La Jolla Voir sur la carte Type d’activité Higher or Secondary Education Establishments Liens Contacter l’organisation Opens in new window Participation aux programmes de R&I de l'UE Opens in new window Réseau de collaboration HORIZON Opens in new window Coût total € 160 130,40
