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Assembly-disassembly-organisation-reassembly of microporous materials

Assembly-disassembly-organisation-reassembly of microporous materials

Objective

Microporous materials are an important class of solid; the two main members of this family are zeolites and metal-organic frameworks (MOFs). Zeolites are industrial solids whose applications range from catalysis, through ion exchange and adsorption technologies to medicine. MOFs are some of the most exciting new materials to have been developed over the last two decades, and they are just beginning to be applied commercially.

Over recent years the applicant’s group has developed new synthetic strategies to prepare microporous materials, called the Assembly-Disassembly-Organisation-Reassembly (ADOR) process. In significant preliminary work the ADOR process has shown to be an extremely important new synthetic methodology that differs fundamentally from traditional solvothermal methods.

In this project I will look to overturn the conventional thinking in materials science by developing methodologies that can target both zeolites and MOF materials that are difficult to prepare using traditional methods – the so-called ‘unfeasible’ materials. The importance of such a new methodology is that it will open up routes to materials that have different properties (both chemical and topological) to those we currently have. Since zeolites and MOFs have so many actual and potential uses, the preparation of materials with different properties has a high chance of leading to new technologies in the medium/long term. To complete the major objective I will look to complete four closely linked activities covering the development of design strategies for zeolites and MOFs (activities 1 & 2), mechanistic studies to understand the process at the molecular level using in situ characterisation techniques (activity 3) and an exploration of potential applied science for the prepared materials (activity 4).
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Host institution

THE UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS

Address

North Street 66 College Gate
Ky16 9aj St Andrews

United Kingdom

Activity type

Higher or Secondary Education Establishments

EU Contribution

€ 2 489 220

Beneficiaries (1)

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THE UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS

United Kingdom

EU Contribution

€ 2 489 220

Project information

Grant agreement ID: 787073

Status

Ongoing project

  • Start date

    1 October 2018

  • End date

    30 September 2023

Funded under:

H2020-EU.1.1.

  • Overall budget:

    € 2 489 220

  • EU contribution

    € 2 489 220

Hosted by:

THE UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS

United Kingdom