Obiettivo The proposed research project "Towards an Ecoefficient Functionalisation of White Phosphorus" is aimed at gaining a fundamental knowledge of the scarcely investigated chemistry of elemental phosphorus. This goal will be approached by studying the metal-mediated activation and functionalisation of white phosphorus. The experimental studies dealing with the stoichiometric, catalytic and electrocatalytic chemistry of P4, will be supplemented, when necessary, by mechanistic and theoretical investigations.The collaborative research activities will be pursued to reach several objectives:The development of the coordination chemistry of white phosphorus and related molecules.The stoichiometric functionalisation of white phosphorus aimed at synthesising via chemical (metal-mediated) and electrochemical methods phosphines or other phosphorus containing species.The development of an ecoefficient "chlorine free" process resulting in the catalytic and electrocatalytic functionalisation of white phosphorus.The optimisation of the electrochemical and catalytic production of organic esters of phosphoric and phosphorous acids as well as of other organophosphorus derivatives of industrial interest.As expected results of this research programme, we can foresee a robust development of the organic and organometallic chemistry of white phosphorus and an ecoefficient approach to the synthesis of organophosphorus derivatives directly from P4 with significant integration between the complementary expertises of the six partners participating in the project. The advantages, which can be anticipated from the successful accomplishment of the proposed "chlorine-free" approach, are the complete elimination of this noxious reagent from the reaction process and the development of innovative catalytic and electrochemical processes for the industrial production of organophosphorus chemicals from P4 with a very reduced environmental impact. Programma(i) IC-INTAS - International Association for the promotion of cooperation with scientists from the independent states of the former Soviet Union (INTAS), 1993- Argomento(i) 3 - Chemistry OPEN - OPEN Call Invito a presentare proposte Data not available Meccanismo di finanziamento Data not available Coordinatore Consiglio Nazionale delle Ricerche Contributo UE Nessun dato Indirizzo Via Jacopo Nardi, 39 50132 Firenze Italia Mostra sulla mappa Costo totale Nessun dato Partecipanti (5) Classifica in ordine alfabetico Classifica per Contributo UE Espandi tutto Riduci tutto Academy of Sciences of Moldova Moldova Contributo UE Nessun dato Indirizzo 8 Academy Street 2028 Kishinev Mostra sulla mappa Costo totale Nessun dato Ministry of Education and Science Kazakstan Contributo UE Nessun dato Indirizzo 142 Kunaev Street 480100 Almaty Mostra sulla mappa Costo totale Nessun dato Russian Academy of Sciences Russia Contributo UE Nessun dato Indirizzo 8 Arbusov Street 420088 Kazan Mostra sulla mappa Costo totale Nessun dato Universidad de Almeria Spagna Contributo UE Nessun dato Indirizzo La Canada de San Urbano, s/n 04071 Almeria Mostra sulla mappa Costo totale Nessun dato Universität Kaiserslautern Germania Contributo UE Nessun dato Indirizzo Erwin-Schroedinger Str. 14 67663 Kaiserslautern Mostra sulla mappa Costo totale Nessun dato