Tandem catalysis for the production of biofuel related chemicals from biomass derived polyols

Projektinformationen

TCPBRCBDP

ID Finanzhilfevereinbarung: 252125

Abgeschlossenes Projekt

Startdatum 1 Mai 2010

Enddatum 30 April 2012

Finanziert unter

• Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)

Gesamtkosten € 181 970,80

EU-Beitrag € 181 970,80

Koordiniert durch

ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE
Switzerland

Ziel

One promising strategy for the production of biofuels from cellulosic, hemicellulosic and lipid materials is to use polyols as a platform. Recent advances have led to direct and (potentially) large scale production of polyols such as ethylene glycol, glycerol and sorbitol. Nevertheless, the downstream production of valuable fuels from polyols is comparatively lacking. In this project we intend to bridge this gap by developing a new strategy that could directly convert polyols into valuable acetals. To achieve this, a one-pot multi-step process through tandem catalysis is envisaged. Acetals will be produced through classical acetalisation reactions between polyols and aldehydes, with the latter being produced in situ from syngas by a tandem Fischer-Tropsch (F-T) reaction and hydroformylation reaction. An efficient, dual functional hybrid catalyst based on a nanoparticle core to which a homogeneous catalyst is tethered that is capable of both F-T and hydroformylation reaction will be designed and synthesized, which to our knowledge represents the first approach of tandem F-T/hydroformylation catalyst. In-situ spectroscopic techniques, such as IR and NMR, will also be applied to study mechanistic aspects of the reactions. The approaches described herein are of high novelty with respect to both biomass conversion and heterogeneous/homogenous catalysis potentially leading to be the more efficient use of renewable resources.

Wissenschaftliches Gebiet

• natural sciences › chemical sciences › organic chemistry › aldehydes
• natural sciences › biological sciences › biochemistry › biomolecules › lipids
• natural sciences › chemical sciences › catalysis
• natural sciences › chemical sciences › organic chemistry › aliphatic compounds
• engineering and technology › industrial biotechnology › biomaterials › biofuels

Programm/Programme

• FP7-PEOPLE - Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)

Thema/Themen

• FP7-PEOPLE-2009-IIF - Marie Curie Action: "International Incoming Fellowships"

Aufforderung zur Vorschlagseinreichung

FP7-PEOPLE-2009-IIF
Andere Projekte für diesen Aufruf anzeigen

Finanzierungsplan

MC-IIF - International Incoming Fellowships (IIF)

Koordinator

ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE

Kontakt Verwaltung

Paul Dyson (Prof.)

• EU-Beitrag: € 181 970,80
• Adresse: BATIMENT CE 3316 STATION 1 ; 1015 Lausanne ; Schweiz
• Region: Schweiz/Suisse/Svizzera › Région lémanique › Vaud
• Aktivitätstyp: Higher or Secondary Education Establishments
• Gesamtkosten: Keine Daten