Functional materials from on-surface linkage of molecular precursors

Project Information

SURFINK

Grant agreement ID: 635919

DOI 10.3030/635919

Project closed

EC signature date 9 June 2015

Start date 1 September 2015

End date 31 August 2020

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 894 723,00

EU contribution € 1 894 723,00

Coordinated by

FUNDACION DONOSTIA INTERNATIONAL PHYSICS CENTER
Spain

Publications

Peer reviewed articles (23)

Electronic decoupling of polyacenes from the underlying metal substrate by sp3 carbon atoms

Author(s): Mohammed S. G. Mohammed, Luciano Colazzo, Roberto Robles, Ruth Dorel, Antonio M. Echavarren, Nicolás Lorente, Dimas G. de Oteyza
Published in: Communications Physics, Issue 3/1, 2020, ISSN 2399-3650
Publisher: Springer Nature
DOI: 10.1038/s42005-020-00425-y

On-Surface Synthesis of a Five-Membered Carbon Ring from a Terminal Alkynyl Bromide: A [4 + 1] Annulation

Author(s): Tao Wang, Yu Pan, Wenzhao Zhang, James Lawrence, Mohammed S. G. Mohammed, Jianmin Huang, Lin Feng, Alejandro Berdonces-Layunta, Dong Han, Qian Xu, Xiaojun Wu, Steven L. Tait, Dimas G. de Oteyza, Junfa Zhu
Published in: The Journal of Physical Chemistry Letters, Issue 11/15, 2020, Page(s) 5902-5907, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.0c01483

Steering alkyne homocoupling with on-surface synthesized metal–organic complexes

Author(s): Mohammed S. G. Mohammed, Luciano Colazzo, Aurelio Gallardo, José A. Pomposo, Pavel Jelínek, Dimas G. de Oteyza
Published in: Chemical Communications, Issue 56/61, 2020, Page(s) 8659-8662, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc03779f

Synthesis of Graphene Nanoribbons on a Kinked Au Surface: Revealing the Frontier Valence Band at the Brillouin Zone Center

Author(s): Afaf El-Sayed, Ignacio Piquero-Zulaica, Zakaria M. Abd El-Fattah, Lukáš Kormoš, Khadiza Ali, Andrew Weber, Jens Brede, Dimas G. de Oteyza, Jorge Lobo-Checa, J. Enrique Ortega, Martina Corso
Published in: The Journal of Physical Chemistry C, Issue 124/28, 2020, Page(s) 15474-15480, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.0c02801

Band Depopulation of Graphene Nanoribbons Induced by Chemical Gating with Amino Groups

Author(s): Jingcheng Li, Pedro Brandimarte, Manuel Vilas-Varela, Nestor Merino-Díez, Cesar Moreno, Aitor Mugarza, Jaime Sáez Mollejo, Daniel Sánchez-Portal, Dimas Garcia de Oteyza, Martina Corso, Aran Garcia-Lekue, Diego Peña, Jose Ignacio Pascual
Published in: ACS Nano, Issue 14/2, 2020, Page(s) 1895-1901, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.9b08162

Width-Dependent Band Gap in Armchair Graphene Nanoribbons Reveals Fermi Level Pinning on Au(111)

Author(s): Néstor Merino-Díez, Aran Garcia-Lekue, Eduard Carbonell-Sanromà, Jingcheng Li, Martina Corso, Luciano Colazzo, Francesco Sedona, Daniel Sánchez-Portal, Jose I. Pascual, Dimas G. de Oteyza
Published in: ACS Nano, Issue 11/11, 2017, Page(s) 11661-11668, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.7b06765

Unraveling the Electronic Structure of Narrow Atomically Precise Chiral Graphene Nanoribbons

Author(s): Néstor Merino-Díez, Jingcheng Li, Aran Garcia-Lekue, Guillaume Vasseur, Manuel Vilas-Varela, Eduard Carbonell-Sanromà, Martina Corso, J. Enrique Ortega, Diego Peña, Jose I. Pascual, Dimas G. de Oteyza
Published in: The Journal of Physical Chemistry Letters, Issue 9/1, 2017, Page(s) 25-30, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.7b02767

Survival of spin state in magnetic porphyrins contacted by graphene nanoribbons

Author(s): Jingcheng Li, Nestor Merino-Díez, Eduard Carbonell-Sanromà, Manuel Vilas-Varela, Dimas G. de Oteyza, Diego Peña, Martina Corso, Jose Ignacio Pascual
Published in: Science Advances, Issue 4/2, 2018, Page(s) eaaq0582, ISSN 2375-2548
Publisher: American Association for the Advancement of Science
DOI: 10.1126/sciadv.aaq0582

Switching from Reactant to Substrate Engineering in the Selective Synthesis of Graphene Nanoribbons

Author(s): Néstor Merino-Díez, Jorge Lobo-Checa, Pawel Nita, Aran Garcia-Lekue, Andrea Basagni, Guillaume Vasseur, Federica Tiso, Francesco Sedona, Pranab K. Das, Jun Fujii, Ivana Vobornik, Mauro Sambi, José Ignacio Pascual, J. Enrique Ortega, Dimas G. de Oteyza
Published in: The Journal of Physical Chemistry Letters, Issue 9/10, 2018, Page(s) 2510-2517, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.8b00796

Electronic Properties of Substitutionally Boron-Doped Graphene Nanoribbons on a Au(111) Surface

Author(s): Eduard Carbonell-Sanromà, Aran Garcia-Lekue, Martina Corso, Guillaume Vasseur, Pedro Brandimarte, Jorge Lobo-Checa, Dimas G. de Oteyza, Jingcheng Li, Shigeki Kawai, Shohei Saito, Shigehiro Yamaguchi, J. Enrique Ortega, Daniel Sánchez-Portal, Jose Ignacio Pascual
Published in: The Journal of Physical Chemistry C, Issue 122/28, 2018, Page(s) 16092-16099, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.8b03748

On-surface synthesis of heptacene on Ag(001) from brominated and non-brominated tetrahydroheptacene precursors

Author(s): Luciano Colazzo, Mohammed S. G. Mohammed, Ruth Dorel, Pawel Nita, Carlos García Fernández, Paula Abufager, Nicolás Lorente, Antonio M. Echavarren, Dimas G. de Oteyza
Published in: Chemical Communications, Issue 54/73, 2018, Page(s) 10260-10263, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc04402c

Π Band Dispersion along Conjugated Organic Nanowires Synthesized on a Metal Oxide Semiconductor

Author(s): Guillaume Vasseur, Mikel Abadia, Luis A. Miccio, Jens Brede, Aran Garcia-Lekue, Dimas G. de Oteyza, Celia Rogero, Jorge Lobo-Checa, J. Enrique Ortega
Published in: Journal of the American Chemical Society, Issue 138/17, 2016, Page(s) 5685-5692, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.6b02151

Tunable Band Alignment with Unperturbed Carrier Mobility of On-Surface Synthesized Organic Semiconducting Wires

Author(s): Andrea Basagni, Guillaume Vasseur, Carlo A. Pignedoli, Manuel Vilas-Varela, Diego Peña, Louis Nicolas, Lucia Vitali, Jorge Lobo-Checa, Dimas G. de Oteyza, Francesco Sedona, Maurizio Casarin, J. Enrique Ortega, Mauro Sambi
Published in: ACS Nano, Issue 10/2, 2016, Page(s) 2644-2651, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.5b07683

Noncovalent Dimerization after Enediyne Cyclization on Au(111)

Author(s): Dimas G. de Oteyza, Alejandro Pérez Paz, Yen-Chia Chen, Zahra Pedramrazi, Alexander Riss, Sebastian Wickenburg, Hsin-Zon Tsai, Felix R. Fischer, Michael F. Crommie, Angel Rubio
Published in: Journal of the American Chemical Society, Issue 138/34, 2016, Page(s) 10963-10967, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.6b05203

Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons

Author(s): Dimas G. de Oteyza, Aran García-Lekue, Manuel Vilas-Varela, Néstor Merino-Díez, Eduard Carbonell-Sanromà, Martina Corso, Guillaume Vasseur, Celia Rogero, Enrique Guitián, Jose Ignacio Pascual, J. Enrique Ortega, Yutaka Wakayama, Diego Peña
Published in: ACS Nano, Issue 10/9, 2016, Page(s) 9000-9008, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.6b05269

Probing the Magnetism of Topological End-States in 5-Armchair Graphene Nanoribbons

Author(s): James Lawrence, Pedro Brandimarte, Alejandro Berdonces-Layunta, Mohammed S. G. Mohammed, Abhishek Grewal, Christopher C. Leon, Daniel Sánchez-Portal, Dimas G. de Oteyza
Published in: ACS Nano, 2020, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.9b10191

Electronic Structure Tunability by Periodic meta -Ligand Spacing in One-Dimensional Organic Semiconductors

Author(s): Ignacio Piquero-Zulaica, Aran Garcia-Lekue, Luciano Colazzo, Claudio K. Krug, Mohammed S. G. Mohammed, Zakaria M. Abd El-Fattah, J. Michael Gottfried, Dimas G. de Oteyza, J. Enrique Ortega, Jorge Lobo-Checa
Published in: ACS Nano, Issue 12/10, 2018, Page(s) 10537-10544, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.8b06536

Controlling the stereospecific bonding motif of Au–thiolate links

Author(s): Luciano Colazzo, Mohammed S. G. Mohammed, Aurelio Gallardo, Zakaria M. Abd El-Fattah, José A. Pomposo, Pavel Jelínek, Dimas G. de Oteyza
Published in: Nanoscale, Issue 11/33, 2019, Page(s) 15567-15575, ISSN 2040-3364
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9nr04383g

Hierarchy in the Halogen Activation During Surface‐Promoted Ullmann Coupling

Author(s): Néstor Merino‐Díez, Alejandro Pérez Paz, Jingcheng Li, Manuel Vilas‐Varela, James Lawrence, Mohammed S. G. Mohammed, Alejandro Berdonces‐Layunta, Ana Barragán, Jose Ignacio Pascual, Jorge Lobo‐Checa, Diego Peña, Dimas G. Oteyza
Published in: ChemPhysChem, Issue 20/18, 2019, Page(s) 2305-2310, ISSN 1439-4235
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.201900633

Controlling a Chemical Coupling Reaction on a Surface: Tools and Strategies for On-Surface Synthesis

Author(s): Sylvain Clair, Dimas G. de Oteyza
Published in: Chemical Reviews, Issue 119/7, 2019, Page(s) 4717-4776, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.8b00601

Keto–enol tautomerization drives the self-assembly of leucoquinizarin on Au(111)

Author(s): Roberto Costantini, Luciano Colazzo, Laura Batini, Matus Stredansky, Mohammed S. G. Mohammed, Simona Achilli, Luca Floreano, Guido Fratesi, Dimas G. de Oteyza, Albano Cossaro
Published in: Chemical Communications, 2020, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc09915h

Single Photon Emission from a Plasmonic Light Source Driven by a Local Field-Induced Coulomb Blockade

Author(s): Christopher C. Leon, Olle Gunnarsson, Dimas G. de Oteyza, Anna Rosławska, Pablo Merino, Abhishek Grewal, Klaus Kuhnke, Klaus Kern
Published in: ACS Nano, 2020, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.9b09299

Transferring axial molecular chirality through a sequence of on-surface reactions

Author(s): Néstor Merino-Díez, Mohammed S. G. Mohammed, Jesús Castro-Esteban, Luciano Colazzo, Alejandro Berdonces-Layunta, James Lawrence, J. Ignacio Pascual, Dimas G. de Oteyza, Diego Peña
Published in: Chemical Science, 2020, ISSN 2041-6520
Publisher: Royal Society of Chemistry

Book chapters (1)

Bottom-Up Fabrication of Atomically Precise Graphene Nanoribbons

Author(s): Martina Corso, Eduard Carbonell-Sanromà, Dimas G. de Oteyza
Published in: On-Surface Synthesis II, 2018, Page(s) 113-152
Publisher: Springer International Publishing
DOI: 10.1007/978-3-319-75810-7_6