Metallocomplexes of macrocyclic compounds for photonic devices

Project Information

METCOPH

Grant agreement ID: 645628

DOI 10.3030/645628

Project closed

EC signature date 6 November 2014

Start date 1 January 2015

End date 31 December 2018

Funded under

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Total cost € 688 500,00

EU contribution € 688 500,00

Coordinated by

INSTYTUT CHEMII FIZYCZNEJ POLSKIEJ AKADEMII NAUK
Poland

Deliverables

Documents, reports (11)

Free-base organic core and cyclometalating ligands

Synthesis of free-base organic core and cyclometalating ligands in order for preparation of MMCs with specific photophysical properties.

Vibrational assignment of investigated compounds

IR and Raman experiments in order to perform a vibrational assignment of investigated compounds. Investigation of spectral manifestation of macrocycle conformations in Raman and fluorescence line narrowing experiments.

A set of energy level diagrams describing the excitation energy deactivation channels in the case of MMCs

Determination of a set of energy level diagrams describing the excitation energy deactivation channels in the case of MMCs. Characterization the relationship between the type of vicinity and quenching of the excited states of the MMCs upon internal and external heavy atom effects.

Progress Report II.

Report on the project's progress.

Quantum-chemical calculations of the MMCs

Performing of quantum-chemical optimization of geometry of various conformers of the MMCs.

Photostable luminescent MMCs

Preparation of photostable luminescent MMCs based on porphyrin and porphycene cores.

MMCs with out-of-plane ligands

Preparation of the last type of MMCs with out-of-plane ligands and MMCs containing two chromospheres with different types of spectral features.

Data of the conformational stability of the MMC

Collecting a data of the conformational stability of the different type of MMCs in polymeric films and on metallic surfaces.

Fluorescence and phosphorescence data

Measurement of fluorescence and phosphorescence data, quantum yields, lifetimes and other photophysical parameters at temperatures ranging from 4,2 to 300 K for novel MMCs.

Progress Report I.

To report on the prject's achieemts after the first 12 months.

Luminescent pincer complexes

Synthesis of luminescent pincer complexes with cyclometalating terdentate for preparation another MMCs of interest.

Other (1)

Scaling of properties of the single emitting MMCs

Determination of scaling of properties of the single emitting MMCs. Characterization of an anisotropy of conformations and energy transfer efficiencies for MMCs. Investigation of a role of the structures of the local environment of subunit on emission of single molecule of MMCs.

Publications

Peer reviewed articles (26)

Magnetic Circular Dichroism of meso -Phenyl-Substituted Pd-Octaethylporphyrins

Author(s): A. Gorski, M. Kijak, E. Zenkevich, V. Knyukshto, A. Starukhin, A. Semeikin, T. Lyubimova, T. Roliński, J. Waluk
Published in: The Journal of Physical Chemistry A, Issue 124/40, 2020, Page(s) 8144-8158, ISSN 1089-5639
Publisher: American Chemical Society
DOI: 10.1021/acs.jpca.0c06669

Photophysical Features of Phthalocyanines Metallocomplexes with Out-of-Plane Ligands

Author(s): A. Starukhin, A. Gorski, V. Knyukshto, M. Kijak, I. Tretyakova, Y. Dovbii, V. Chernii
Published in: Universal Journal of Physics and Application, Issue 11/4, 2017, Page(s) 109-114, ISSN 2331-6535
Publisher: Horizon Research Publishing Corporation
DOI: 10.13189/ujpa.2017.110403

Activity of Zn and Mg phthalocyanines and porphyrazines in amyloid aggregation of insulin

Author(s): V. Kovalska, S. Chernii, M. Losytskyy, J. Ostapko, I. Tretyakova, A. Gorski, V. Chernii, S. Yarmoluk
Published in: Journal of Molecular Recognition, Issue 30 August 2017, 2017, Page(s) e2660, ISSN 0952-3499
Publisher: John Wiley & Sons Inc.
DOI: 10.1002/jmr.2660

Photophysical study of meso-phenothiazinyl-porphyrins metallocomplexes

Author(s): Aleksander Starukhin, Aleksander Gorski, Valery Knyukshto, Andrei Panarin, Tatiana Pavich, Luiza Gaina, Emese Gal
Published in: EPJ Web of Conferences, Issue 161, 2017, Page(s) 03017, ISSN 2100-014X
Publisher: EDP Sciences, http://publications.edpsciences.org/
DOI: 10.1051/epjconf/201716103017

Spectral manifestation of distorted forms metalloporphyrins at low temperatures

Author(s): Aleksander Starukhin, Aleksander Gorski, Michal Kijak
Published in: EPJ Web of Conferences, Issue 161, 2017, Page(s) 01011, ISSN 2100-014X
Publisher: EDP Sciences, http://publications.edpsciences.org/
DOI: 10.1051/epjconf/201716101011

Radiative Deactivation of Lowest Singlet and Triplet Excited States of Water-Soluble Porphyrins

Author(s): V. N. Knyukshto, A. S. Starukhin, M. M. Kruk, A. V. Gorskii
Published in: Journal of Applied Spectroscopy, Issue 84/6, 2018, Page(s) 960-965, ISSN 0021-9037
Publisher: Kluwer Academic Publishers
DOI: 10.1007/s10812-018-0571-2

Mössbauer spectroscopy as a probe of electric field in heme pocket of deoxyheme proteins: theoretical approach

Author(s): Alexandr Gorski, Aleksandr Starukhin, Solomon S. Stavrov
Published in: Journal of Radioanalytical and Nuclear Chemistry, Issue 313/1, 2017, Page(s) 141-144, ISSN 0236-5731
Publisher: Akademiai Kiado
DOI: 10.1007/s10967-017-5294-y

Mitochondria Targeting with Luminescent Rhenium(I) Complexes

Author(s): Joanna Skiba, Tytus Bernaś, Damian Trzybiński, Krzysztof Woźniak, Giarita Ferraro, Daniela Marasco, Antonello Merlino, Marsel Shafikov, Rafał Czerwieniec, Konrad Kowalski
Published in: Molecules, Issue 22/12, 2017, Page(s) 809, ISSN 1420-3049
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules22050809

Resonance Raman spectroscopy study of protonated porphyrin

Author(s): A. Gorski, A. Starukhin, S. Stavrov, S. Gawinkowski, J. Waluk
Published in: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Issue 173, 2017, Page(s) 350-355, ISSN 1386-1425
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.saa.2016.09.038

β-ketoenole dyes: Synthesis and study as fluorescent sensors for protein amyloid aggregates

Author(s): Vladyslava Kovalska, Svitlana Chernii, Mykhaylo Losytskyy, Yan Dovbii, Iryna Tretyakova, Rafal Czerwieniec, Victor Chernii, Sergiy Yarmoluk, Sergiy Volkov
Published in: Dyes and Pigments, Issue 132, 2016, Page(s) 274-281, ISSN 0143-7208
Publisher: Elsevier BV
DOI: 10.1016/j.dyepig.2016.04.053

Design of functionalized β-ketoenole derivatives as efficient fluorescent dyes for detection of amyloid fibrils

Author(s): Vladyslava Kovalska, Svitlana Chernii, Mykhaylo Losytskyy, Iryna Tretyakova, Yan Dovbii, Alexandr Gorski, Victor Chernii, Rafal Czerwieniec, Sergiy Yarmoluk
Published in: New Journal of Chemistry, Issue 42/16, 2018, Page(s) 13308-13318, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8nj01020j

Wavelength dependence of the efficiency of singlet oxygen generation upon photoexcitation of photosensitizers

Author(s): A. Starukhin, V. Knyukshto, V. Plavskii, A. Gorski, J. Solarski
Published in: EPJ Web of Conferences, Issue 132, 2017, Page(s) 02019, ISSN 2100-014X
Publisher: EDP Sciences - Web of Conferences
DOI: 10.1051/epjconf/201713202019

Spectral manifestation of substitution of out-of-plane ligands in metallophtalocyanines

Author(s): A. Starukhin, V. Knyukshto, A. Gorski, V. Chernii, I. Tretyakova, M. Kijak, P. Kowalska
Published in: EPJ Web of Conferences, Issue 132, 2017, Page(s) 03044, ISSN 2100-014X
Publisher: EDP Sciences, http://publications.edpsciences.org/
DOI: 10.1051/epjconf/201713203044

Spectral features of conjugated bichromophores: porphyrins with curcumin

Author(s): Aleksandr Starukhin, Aleksander Gorski, Tatsiana Pavich, Valerii Kniukshto
Published in: EPJ Web of Conferences, Issue 190, 2018, Page(s) 04023, ISSN 2100-014X
Publisher: EDP Sciences, http://publications.edpsciences.org/
DOI: 10.1051/epjconf/201819004023

Influence of solid matrices on spectral features of metalloporphyrins

Author(s): Aleksandr Starukhin, Aleksander Gorski, Michal Kijak
Published in: EPJ Web of Conferences, Issue 190, 2018, Page(s) 03013, ISSN 2100-014X
Publisher: EDP Sciences, http://publications.edpsciences.org/
DOI: 10.1051/epjconf/201819003013

Spectral Distortions of Metalloporphyrin Forms at Low Temperatures

Author(s): A. S. Starukhin, A. V. Gorski, M. Z. Kijak
Published in: Bulletin of the Russian Academy of Sciences: Physics, Issue 82/12, 2018, Page(s) 1560-1564, ISSN 1062-8738
Publisher: Allerton Press Inc.
DOI: 10.3103/s1062873818120225

Wide-Range Spectral Diffusion in Single Mg-Tetraazaporphyrin Molecules in a Polymer Matrix at Cryogenic Temperatures

Author(s): A. O. Savostianov, I. Yu. Eremchev, A. A. Gorshelev, A. V. Naumov, A. S. Starukhin
Published in: JETP Letters, Issue 107/7, 2018, Page(s) 406-411, ISSN 0021-3640
Publisher: Maik Nauka/Interperiodica Publishing
DOI: 10.1134/s002136401807007x

Structural and time-domain peculiarities of the fluorescence excitation spectra of single Mg-TAP in a polymer at low temperatures

Author(s): Aleksandr Savostianov, Ivan Eremchev, Alexei Gorshelev, Sergei Orlov, Oleg Korotayev, Andrei Naumov, Aleksandr Starukhin
Published in: EPJ Web of Conferences, Issue 190, 2018, Page(s) 04019, ISSN 2100-014X
Publisher: EDP Sciences, http://publications.edpsciences.org/
DOI: 10.1051/epjconf/201819004019

Substitution of Metallocenes with [2.2]Paracyclophane to Enable Confocal Microscopy Imaging in Living Cells

Author(s): Joanna Skiba, Claudia Schmidt, Petra Lippmann, Philipp Ensslen, Hans-Achim Wagenknecht, Rafał Czerwieniec, Fabian Brandl, Ingo Ott, Tytus Bernaś, Barbara Krawczyk, Dominik Szczukocki, Konrad Kowalski
Published in: European Journal of Inorganic Chemistry, Issue 2017/2, 2017, Page(s) 297-305, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201600281

Temperature dependent steric hindrance effects in triplet state relaxation of meso-phenyl-substituted Pd-octaethylporphyrins

Author(s): Alexandr Gorski, Valery Knyukshto, Eduard Zenkevich, Alexander Starukhin, Michał Kijak, Jędrzej Solarski, Alexander Semeikin, Tatjana Lyubimova
Published in: Journal of Photochemistry and Photobiology A: Chemistry, Issue 354, 2018, Page(s) 101-111, ISSN 1010-6030
Publisher: Elsevier BV
DOI: 10.1016/j.jphotochem.2017.09.002

TADF Material Design: Photophysical Background and Case Studies Focusing on Cu I and Ag I Complexes

Author(s): Hartmut Yersin, Rafal Czerwieniec, Marsel Z. Shafikov, Alfiya F. Suleymanova
Published in: ChemPhysChem, Issue 18/24, 2017, Page(s) 3508-3535, ISSN 1439-4235
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.201700872

Design of Conformationally Distorted Donor–Acceptor Dyads Showing Efficient Thermally Activated Delayed Fluorescence

Author(s): Gereon A. Sommer, Larisa N. Mataranga-Popa, Rafal Czerwieniec, Thomas Hofbeck, Herbert H. H. Homeier, Thomas J. J. Müller, Hartmut Yersin
Published in: The Journal of Physical Chemistry Letters, Issue 9/13, 2018, Page(s) 3692-3697, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.8b01511

Luminescent fac -[Re(CO) 3 (phen)] carboxylato complexes with non-steroidal anti-inflammatory drugs: synthesis and mechanistic insights into the in vitro anticancer activity of fac -[Re(CO) 3 (phen)(aspirin)]

Author(s): Joanna Skiba, Aleksandra Kowalczyk, Paweł Stączek, Tytus Bernaś, Damian Trzybiński, Krzysztof Woźniak, Ulrich Schatzschneider, Rafał Czerwieniec, Konrad Kowalski
Published in: New Journal of Chemistry, Issue 43/2, 2019, Page(s) 573-583, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8nj05494k

SYNTHESIS OF DEHYDROACETIC ACID DERIVATIVES WITH CHROMOPHORIC CHAINS AND THEIR COMPLEXES WITH ZIRCONIUM PHTHALOCYANINE

Author(s): Ya.M.Dovbii, V.Ya.Chernii, I.M.Tretyakova, A.V.Gorski, A.S.Starukhin, S.V.Volkov
Published in: Ukrainian Chemistry Journal, Issue 12, 2015, Page(s) 79-82, ISSN 0041-6045
Publisher: National'na Akademiya Nauk Ukrainy

Design Strategy for Ag(I)-Based Thermally Activated Delayed Fluorescence Reaching an Efficiency Breakthrough

Author(s): Marsel Z. Shafikov, Alfiya F. Suleymanova, Rafał Czerwieniec, and Hartmut Yersin
Published in: Chemistry of Materials, 2017, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.6b05175

Cu(I) complexes – Thermally activated delayed fluorescence. Photophysical approach and material design

Author(s): Rafał Czerwieniec, Markus J. Leitl, Herbert H.H. Homeier, Hartmut Yersin
Published in: Coordination Chemistry Reviews, 2016, Page(s) 2–28, ISSN 0010-8545
Publisher: Elsevier BV
DOI: 10.1016/j.ccr.2016.06.016