Gain by Strain: Precise Cuts of Cyclopropanes as Key to Molecular Complexity

Informazioni relative al progetto

GAINBYSTRAIN

ID dell’accordo di sovvenzione: 648711

DOI 10.3030/648711

Progetto chiuso

Data della firma CE 22 Aprile 2015

Data di avvio 1 Luglio 2015

Data di completamento 30 Giugno 2021

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale € 1 994 250,00

Contributo UE € 1 994 250,00

Coordinato da

TECHNISCHE UNIVERSITAET BRAUNSCHWEIG
Germany

Pubblicazioni

Peer reviewed articles (18)

Ferrocenyl-substituted tetrahydrothiophenes via formal [3 + 2]-cycloaddition reactions of ferrocenyl thioketones with donor–acceptor cyclopropanes

Autori: Grzegorz Mlostoń, Mateusz Kowalczyk, André U Augustin, Peter G Jones, Daniel B Werz
Pubblicato in: Beilstein Journal of Organic Chemistry, Numero 16, 2020, Pagina/e 1288-1295, ISSN 1860-5397
Editore: Beilstein-Institut
DOI: 10.3762/bjoc.16.109

New Dyes Based on Extended Fulvene Motifs: Synthesis through Redox Reactions of Naphthoquinones with Donor–Acceptor Cyclopropanes and Their Spectroelectrochemical Behavior

Autori: Alexander Lücht, Sebastian Sobottka, Lukas J. Patalag, Peter G. Jones, Hans‐Ulrich Reissig, Biprajit Sarkar, Daniel B. Werz
Pubblicato in: Chemistry – A European Journal, Numero 25/44, 2019, Pagina/e 10359-10365, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201900764

Electrocatalytic Activation of Donor–Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(sp 3 )−C(sp 3 ) Cleavage Mode

Autori: Simon Kolb, Martin Petzold, Felix Brandt, Peter G. Jones, Christoph R. Jacob, Daniel B. Werz
Pubblicato in: Angewandte Chemie International Edition, Numero 60/29, 2021, Pagina/e 15928-15934, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202101477

Protic Ionic Liquid as Reagent, Catalyst, and Solvent: 1‐Methylimidazolium Thiocyanate

Autori: Ivan A. Andreev, Nina K. Ratmanova, André U. Augustin, Olga A. Ivanova, Irina I. Levina, Victor N. Khrustalev, Daniel B. Werz, Igor V. Trushkov
Pubblicato in: Angewandte Chemie International Edition, Numero 60/14, 2021, Pagina/e 7927-7934, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202016593

Functionalization of Sydnones with Donor‐Acceptor Cyclopropanes, Cyclobutanes, and Michael Acceptors

Autori: Nils L. Ahlburg, Tyll Freese, Simon Kolb, Sebastian Mummel, Andreas Schmidt, Daniel B. Werz
Pubblicato in: European Journal of Organic Chemistry, Numero 2021/10, 2021, Pagina/e 1603-1606, ISSN 1434-193X
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202100070

Regio‐ and Diastereoselective Dimerization of Diazo Carbonyls: A Cooperative Catalytic Approach to Complex Scaffolds with Four Contiguous Stereocenters

Autori: Martin Petzold, Andre Günther, Peter G. Jones, Daniel B. Werz
Pubblicato in: Chemistry – A European Journal, Numero 26/49, 2020, Pagina/e 11119-11123, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001548

Stereospecific Reactions of Donor-Acceptor Cyclopropanes with Thioketones: Access to Highly Substituted Tetrahydrothiophenes

Autori: André U. Augustin, Maximilian Sensse, Peter G. Jones, Daniel B. Werz
Pubblicato in: Angewandte Chemie International Edition, Numero 56/45, 2017, Pagina/e 14293-14296, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201708346

Reactions of Donor-Acceptor Cyclopropanes with Naphthoquinones: Redox and Lewis Acid Catalysis Working in Concert

Autori: Alexander Lücht, Lukas J. Patalag, André U. Augustin, Peter G. Jones, Daniel B. Werz
Pubblicato in: Angewandte Chemie International Edition, Numero 56/35, 2017, Pagina/e 10587-10591, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201703732

Ring-Opening Regio-, Diastereo-, and Enantioselective 1,3-Chlorochalcogenation of Cyclopropyl Carbaldehydes

Autori: Jan Wallbaum, Lennart K. B. Garve, Peter G. Jones, Daniel B. Werz
Pubblicato in: Chemistry - A European Journal, 2016, ISSN 1521-3765
Editore: Wiley-VCH
DOI: 10.1002/chem.201605265

Ring-Opening 1,3-Halochalcogenation of Cyclopropane Dicarboxylates

Autori: Jan Wallbaum, Lennart K. B. Garve, Peter G. Jones, Daniel B. Werz
Pubblicato in: Organic Letters, 2017, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.6b03375

Ring‐Opening 1,3‐Aminochalcogenation of Donor–Acceptor Cyclopropanes: A Three‐Component Approach

Autori: André U. Augustin, Peter G. Jones, Daniel B. Werz
Pubblicato in: Chemistry – A European Journal, Numero 25/50, 2019, Pagina/e 11620-11624, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201902160

Uncovering the Neglected Similarities of Arynes and Donor-Acceptor Cyclopropanes

Autori: Daniel B. Werz, Akkattu T. Biju
Pubblicato in: Angewandte Chemie International Edition, Numero 59/9, 2020, Pagina/e 3385-3398, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201909213

(4 + 3)-Cycloaddition of Donor–Acceptor Cyclopropanes with Thiochalcones: A Diastereoselective Access to Tetrahydrothiepines

Autori: André U. Augustin, J. Luca Merz, Peter G. Jones, Grzegorz Mlostoń, Daniel B. Werz
Pubblicato in: Organic Letters, Numero 21/23, 2019, Pagina/e 9405-9409, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.9b03623

(3+3)-Annulation of Carbonyl Ylides with Donor-Acceptor Cyclopropanes: Synergistic Dirhodium(II) and Lewis Acid Catalysis

Autori: Martin Petzold, Peter G. Jones, Daniel B. Werz
Pubblicato in: Angewandte Chemie International Edition, Numero 58/19, 2019, Pagina/e 6225-6229, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201814409

Reactions of 3,3′-Linked Bispyrroles with Carbon Electrophiles

Autori: Alexander Lücht, Peter G. Jones, Daniel B. Werz
Pubblicato in: European Journal of Organic Chemistry, Numero 2019/31-32, 2019, Pagina/e 5254-5260, ISSN 1434-193X
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.201900106

Kinetic Studies of Donor-Acceptor Cyclopropanes: The Influence of Structural and Electronic Properties on the Reactivity

Autori: Alexander Kreft, Alexander Lücht, Jörg Grunenberg, Peter G. Jones, Daniel B. Werz
Pubblicato in: Angewandte Chemie International Edition, Numero 58/7, 2019, Pagina/e 1955-1959, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201812880

Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis

Autori: André U. Augustin, Marius Busse, Peter G. Jones, Daniel B. Werz
Pubblicato in: Organic Letters, Numero 20/3, 2018, Pagina/e 820-823, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.7b03961

Ketenedithioacetals as Surrogates for the Formal Insertion of Ketenes into Donor–Acceptor Cyclopropanes

Autori: Alexander Lücht, Alexander Kreft, Peter G. Jones, Daniel B. Werz
Pubblicato in: European Journal of Organic Chemistry, Numero 2020/17, 2020, Pagina/e 2560-2564, ISSN 1434-193X
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202000233