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HYBRID QUANTUM-DOT/TWO-DIMENSIONAL MATERIALS PHOTOVOLTAIC CELLS

Objectif

The development of high-efficiency and low-cost solar cells is one of the most crucial challenges to secure a clean and sustainable energy source. The novel and tunable optoelectronic properties of nanomaterials are a very promising but still challenging route to achieve this goal. In this project, we propose to combine the advantages of two important nanoscale materials, semiconductor quantum dots (QD) and two-dimensional atomic layered (2-D) materials, to realize high-efficiency hybrid solar cells. Quantum dots are one of the best absorbing and carrier photogenerators due to multiple exciton generation and their size-tunable and direct band gap, however, their poor dot-to-dot conductivity has been a major limitation for photovoltaic devices. We propose to overcome this limitation by intercalating 2-D materials that have shown high charge mobility and strong optoelectronic properties. We propose a tandem configuration based on a stack of QD layers for strong carrier photogeneration, with intercalated 2-D atomic layers for efficient charge and photocurrent extraction. We will study the charge transfer and separation at the interface of QDs and 2-D layers, both of which are strongly affected by quantum confinement. The co-supervisors of this project, Prof. Konstantatos and Prof. Koppens at ICFO, have demonstrated a QD/2-D(graphene) phototransistor with a photoresponse up to 5 orders of magnitude higher than phototransistors based on single graphene or MoS2 atomic layers without QDs, showing the potential of QD/2-D hybrid devices for photovoltaics. In addition to QDs, we will also use small band gap materials, such as phosphorene and other 2-D semiconductors that can harvest energy from infrared hot sources in dark conditions. The proposed hybrid QD/2-D solar cell architecture can have a strong technological impact since both materials can be produced in large scale by chemical synthesis and surpass the performance of current photovoltaic technologies.

Coordinateur

FUNDACIO INSTITUT DE CIENCIES FOTONIQUES
Contribution nette de l'UE
€ 158 121,60
Adresse
AVINGUDA CARL FRIEDRICH GAUSS 3
08860 Castelldefels
Espagne

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Région
Este Cataluña Barcelona
Type d’activité
Research Organisations
Liens
Coût total
€ 158 121,60