Periodic Reporting for period 1 - MANGANOXI (The development of manganese-based alkene epoxidation, cis-dihydroxylation and alkane C-H oxidation catalysts)
Période du rapport: 2015-09-01 au 2017-08-31
The overall objectives of the project were to (i) investigate whether the addition of Lewis acid additives to a catalytic system that is known to be active in oxidative catalysis, which we have previously worked on, would result in an increase in reactivity; (ii) to develop a range of new ligand architectures to coordinate metals in which we included triazole moieties generated through ‘click’ reactions; the rationale for including the ‘click’ triazoles being that that they provided a similar structural motif to the commonly used pyridine ligand in other oxidative systems, allowed for modular syntheses to be developed and ultimately might provide a means of attaching the catalyst to solid supports; (iii) in the final objective we envisioned the use of solid supports to develop routes to heterogenised versions of the catalytic systems developed in (ii) so that they could be applied in flow reactors.