Stereocontrolled Polymerisation: New Frontiers in Synthesis and Supramolecular Self Assembly

Informazioni relative al progetto

STEREOPOL

ID dell’accordo di sovvenzione: 681559

DOI 10.3030/681559

Progetto chiuso

Data della firma CE 29 Aprile 2016

Data di avvio 1 Settembre 2016

Data di completamento 30 Aprile 2023

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale € 2 074 731,00

Contributo UE € 2 074 731,00

Coordinato da

THE UNIVERSITY OF BIRMINGHAM
United Kingdom

Pubblicazioni

Peer reviewed articles (29)

Ultra‐Tough Elastomers from Stereochemistry‐Directed Hydrogen Bonding in Isosorbide‐Based Polymers

Autori: Shannon R. Petersen; Hannah Prydderch; Joshua C. Worch; Connor J. Stubbs; Zilu Wang; Jiayi Yu; Maria C. Arno; Andrey V. Dobrynin; Matthew L. Becker; Andrew P. Dove
Pubblicato in: Angewandte Chemie International Edition, Numero 3, 2022, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202115904

Sugar-Based Polymers with Stereochemistry-Dependent Degradability and Mechanical Properties

Autori: Connor J. Stubbs; Joshua C. Worch; Hannah Prydderch; Zilu Wang; Robert T. Mathers; Andrey V. Dobrynin; Matthew L. Becker; Andrew P. Dove
Pubblicato in: Journal of the American Chemical Society, Numero 1, 2022, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.1c10278

Concomitant control of mechanical properties and degradation in resorbable elastomer-like materials using stereochemistry and stoichiometry for soft tissue engineering

Autori: Mary Beth Wandel, Craig A. Bell, Jiayi Yu, Maria C. Arno, Nathan Z. Dreger, Yen-Hao Hsu, Anaïs Pitto-Barry, Joshua C. Worch, Andrew P. Dove, Matthew L. Becker
Pubblicato in: Nature Communications, Numero 12/1, 2021, Pagina/e 446, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-020-20610-5

Using Stereochemistry to Control Mechanical Properties in Thiol-Yne Click-Hydrogels.

Autori: Laura J. Macdougall; Maria M. Pérez-Madrigal; Joshua E Shaw; Joshua C. Worch; Chris Sammon; Stephen M. Richardson; Andrew P. Dove
Pubblicato in: 1521-3757, Numero 1, 2021, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202107161

Click Nucleophilic Conjugate Additions to Activated Alkynes: Exploring Thiol-yne, Amino-yne, and Hydroxyl-yne Reactions from (Bio)Organic to Polymer Chemistry.

Autori: Joshua C. Worch; Connor J. Stubbs; Matthew J. Price; Andrew P. Dove
Pubblicato in: Chemical Reviews, Numero 1, 2021, ISSN 0009-2665
Editore: American Chemical Society
DOI: 10.1021/acs.chemrev.0c01076

Intrinsically Re-curable Photopolymers Containing Dynamic Thiol-Michael Bonds

Autori: Connor J. Stubbs; Anissa L. Khalfa; Viviane Chiaradia; Joshua C. Worch; Andrew P. Dove
Pubblicato in: Crossref, Numero 3, 2022, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.2c03525

Selective Reactivity of Myrcene for Vat Photopolymerization 3D Printing and Postfabrication Surface Modification

Autori: Andrew C. Weems, Kayla R. Delle Chiaie, Rachel Yee, Andrew P. Dove
Pubblicato in: Biomacromolecules, Numero 21/1, 2020, Pagina/e 163-170, ISSN 1525-7797
Editore: American Chemical Society
DOI: 10.1021/acs.biomac.9b01125

Stereochemistry-Controlled Mechanical Properties and Degradation in 3D-Printable Photosets.

Autori: Anissa L Khalfa; Matthew L. Becker; Andrew P. Dove
Pubblicato in: Journal of the American Chemical Society, Numero 3, 2021, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.1c06960

Stereoselective ROP of rac- and meso-Lactides Using Achiral TBD as Catalyst

Autori: Sébastien Moins, Sébastien Hoyas, Vincent Lemaur, Beste Orhan, Kayla Delle Chiaie, Roberto Lazzaroni, Daniel Taton, Andrew P. Dove, Olivier Coulembier
Pubblicato in: Catalysts, Numero 10/6, 2020, Pagina/e 620, ISSN 2073-4344
Editore: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/catal10060620

Elastomeric polyamide biomaterials with stereochemically tuneable mechanical properties and shape memory

Autori: Joshua C. Worch, Andrew C. Weems, Jiayi Yu, Maria C. Arno, Thomas R. Wilks, Robert T. R. Huckstepp, Rachel K. O’Reilly, Matthew L. Becker, Andrew P. Dove
Pubblicato in: Nature Communications, Numero 11/1, 2020, Pagina/e 3250, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-020-16945-8

Understanding the CDSA of poly(lactide) containing triblock copolymers

Autori: Wei Yu, Maria Inam, Joseph R. Jones, Andrew P. Dove, Rachel K. O'Reilly
Pubblicato in: Polymer Chemistry, Numero 8/36, 2017, Pagina/e 5504-5512, ISSN 1759-9954
Editore: Royal Society of Chemistry
DOI: 10.1039/C7PY01056G

Unlocking the Potential of Poly( Ortho Ester)s: A General Catalytic Approach to the Synthesis of Surface-Erodible Materials

Autori: Mathieu J.-L. Tschan, Nga Sze Ieong, Richard Todd, Jack Everson, Andrew P. Dove
Pubblicato in: Angewandte Chemie International Edition, Numero 56/52, 2017, Pagina/e 16664-16668, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201709934

Precision Epitaxy for Aqueous 1D and 2D Poly(ε-caprolactone) Assemblies

Autori: Maria C. Arno, Maria Inam, Zachary Coe, Graeme Cambridge, Laura J. Macdougall, Robert Keogh, Andrew P. Dove, Rachel K. O’Reilly
Pubblicato in: Journal of the American Chemical Society, Numero 139/46, 2017, Pagina/e 16980-16985, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.7b10199

Poly(oligo(ethylene glycol) vinyl acetate)s: A Versatile Class of Thermoresponsive and Biocompatible Polymers

Autori: Guillaume G. Hedir, Maria C. Arno, Marvin Langlais, Jonathan T. Husband, Rachel K. O'Reilly, Andrew P. Dove
Pubblicato in: Angewandte Chemie International Edition, Numero 56/31, 2017, Pagina/e 9178-9182, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201703763

1D vs. 2D shape selectivity in the crystallization-driven self-assembly of polylactide block copolymers

Autori: Maria Inam, Graeme Cambridge, Anaïs Pitto-Barry, Zachary P. L. Laker, Neil R. Wilson, Robert T. Mathers, Andrew P. Dove, Rachel K. O'Reilly
Pubblicato in: Chemical Science, Numero 8/6, 2017, Pagina/e 4223-4230, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/C7SC00641A

pH-Responsive, Functionalizable Spyrocyclic Polycarbonate: A Versatile Platform for Biocompatible Nanoparticles

Autori: Maria C. Arno, Ruairí P. Brannigan, Gina M. Policastro, Matthew L. Becker, Andrew P. Dove
Pubblicato in: Biomacromolecules, Numero 19/8, 2018, Pagina/e 3427-3434, ISSN 1525-7797
Editore: American Chemical Society
DOI: 10.1021/acs.biomac.8b00744

Uniform Biodegradable Fiber-Like Micelles and Block Comicelles via “Living” Crystallization-Driven Self-Assembly of Poly( l -lactide) Block Copolymers: The Importance of Reducing Unimer Self-Nucleation via Hydrogen Bond Disruption

Autori: Yunxiang He, Jean-Charles Eloi, Robert L. Harniman, Robert M. Richardson, George R. Whittell, Robert T. Mathers, Andrew P. Dove, Rachel K. O’Reilly, Ian Manners
Pubblicato in: Journal of the American Chemical Society, Numero 141/48, 2019, Pagina/e 19088-19098, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.9b09885

Controlling the Size of Two-Dimensional Polymer Platelets for Water-in-Water Emulsifiers

Autori: Maria Inam, Joseph R. Jones, Maria M. Pérez-Madrigal, Maria C. Arno, Andrew P. Dove, Rachel K. O’Reilly
Pubblicato in: ACS Central Science, Numero 4/1, 2017, Pagina/e 63-70, ISSN 2374-7943
Editore: American Chemical Society
DOI: 10.1021/acscentsci.7b00436

Isoselective Ring-Opening Polymerization of rac -Lactide from Chiral Takemoto’s Organocatalysts: Elucidation of Stereocontrol

Autori: Beste Orhan, Mathieu J.-L. Tschan, Anne-Laure Wirotius, Andrew P. Dove, Olivier Coulembier, Daniel Taton
Pubblicato in: ACS Macro Letters, Numero 7/12, 2018, Pagina/e 1413-1419, ISSN 2161-1653
Editore: American Chemical Society
DOI: 10.1021/acsmacrolett.8b00852

Unsaturated Poly(ester-urethanes) with Stereochemically Dependent Thermomechanical Properties

Autori: Connor J. Stubbs, Joshua C. Worch, Hannah Prydderch, Matthew L. Becker, Andrew P. Dove
Pubblicato in: Macromolecules, Numero 53/1, 2019, Pagina/e 174-181, ISSN 0024-9297
Editore: American Chemical Society
DOI: 10.1021/acs.macromol.9b01700

Exploiting the role of nanoparticle shape in enhancing hydrogel adhesive and mechanical properties

Autori: Maria C. Arno, Maria Inam, Andrew C. Weems, Zehua Li, Abbie L. A. Binch, Christopher I. Platt, Stephen M. Richardson, Judith A. Hoyland, Andrew P. Dove, Rachel K. O’Reilly
Pubblicato in: Nature Communications, Numero 11/1, 2020, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-020-15206-y

Stereochemical enhancement of polymer properties

Autori: Joshua C. Worch, Hannah Prydderch, Sètuhn Jimaja, Panagiotis Bexis, Matthew L. Becker, Andrew P. Dove
Pubblicato in: Nature Reviews Chemistry, Numero 3/9, 2019, Pagina/e 514-535, ISSN 2397-3358
Editore: Springer-Nature
DOI: 10.1038/s41570-019-0117-z

Self-healing, stretchable and robust interpenetrating network hydrogels

Autori: Laura J. Macdougall, Maria M. Pérez-Madrigal, Joshua E. Shaw, Maria Inam, Judith A. Hoyland, Rachel O'Reilly, Stephen M. Richardson, Andrew P. Dove
Pubblicato in: Biomaterials Science, Numero 6/11, 2018, Pagina/e 2932-2937, ISSN 2047-4830
Editore: Royal Society of Chemistry
DOI: 10.1039/c8bm00872h

Nonswelling Thiol–Yne Cross-Linked Hydrogel Materials as Cytocompatible Soft Tissue Scaffolds

Autori: Laura J. Macdougall, Maria M. Pérez-Madrigal, Maria C. Arno, Andrew P. Dove
Pubblicato in: Biomacromolecules, Numero 19/5, 2017, Pagina/e 1378-1388, ISSN 1525-7797
Editore: American Chemical Society
DOI: 10.1021/acs.biomac.7b01204

Design of synthetic extracellular matrices for probing breast cancer cell growth using robust cyctocompatible nucleophilic thiol-yne addition chemistry

Autori: Laura J. Macdougall, Katherine L. Wiley, April M. Kloxin, Andrew P. Dove
Pubblicato in: Biomaterials, Numero 178, 2018, Pagina/e 435-447, ISSN 0142-9612
Editore: Pergamon Press Ltd.
DOI: 10.1016/j.biomaterials.2018.04.046

Synthesis of Degradable Poly(vinyl alcohol) by Radical Ring-Opening Copolymerization and Ice Recrystallization Inhibition Activity

Autori: Guillaume Hedir, Christopher Stubbs, Phillip Aston, Andrew P. Dove, Matthew I. Gibson
Pubblicato in: ACS Macro Letters, Numero 6/12, 2017, Pagina/e 1404-1408, ISSN 2161-1653
Editore: American Chemical Society
DOI: 10.1021/acsmacrolett.7b00905

Renewable and recyclable covalent adaptable networks based on bio-derived lipoic acid

Autori: Maher A. Alraddadi; Viviane Chiaradia; Connor J. Stubbs; Joshua C. Worch; Andrew P. Dove
Pubblicato in: Polymer Chemistry, Numero 2, 2021, ISSN 1759-9954
Editore: Royal Society of Chemistry
DOI: 10.1039/d1py00754h

Harnessing the Chemical Diversity of the Natural Product Magnolol for the Synthesis of Renewable, Degradable Neolignan Thermosets with Tunable Thermomechanical Characteristics and Antioxidant Activity

Autori: Kevin T. Wacker, Andrew C. Weems, Soon-Mi Lim, Sarosh Khan, Simcha E. Felder, Andrew P. Dove, Karen L. Wooley
Pubblicato in: Biomacromolecules, Numero 20/1, 2018, Pagina/e 109-117, ISSN 1525-7797
Editore: American Chemical Society
DOI: 10.1021/acs.biomac.8b00771

Understanding structure–property relationships of main chain cyclopropane in linear polyesters

Autori: Connor J. Stubbs, Andrew P. Dove
Pubblicato in: Polymer Chemistry, Numero 11/39, 2020, Pagina/e 6251-6258, ISSN 1759-9954
Editore: Royal Society of Chemistry
DOI: 10.1039/d0py01004a