Risultati finali
A brief description of the shaping techniques developed in the projects, their main drawbacks and potentials
Conditions for optimal drying process for MOF synthesis by spray-dryingThe report describe briefly the spray drying process forMOF synthesis, the conditions used and the main characteristica of the products formed
Description of shaping processes and shaped productsBrief report on the various shaping techniques developed in the project and the main characteristica of the shaped products
Optimization of spray-drying processes for high yield production of divalent MOFsA document describing briefly the spray drying process and the ways to optimize this towards high yield and high quality of the product
NPMs specification sheets for production quality control and recommendation for useThe report describe how a specification sheet following the various NPM products can look like and which data is should contain
Report on the synthesis of second generation MOF in water and in solvent with recyclingA brief report describing the main results and material properties of NPMs produced in water and with solvent recycling
Public report on the performances on shaped materials at laboratory scaleBrief report on the performance and physical properties of a selection of the shaped bodies prepared in the project
Report on the quality control of production processes at kg-scaleA report that describes the various techniques used to obtain physical and performance information abount NPM products to check their quality
Conditions for supercritical CO2 washingThe report describes the supercritical washing technique, the conditions used and the characteristica of the wasing process as compared to conventional techniques
A workshop will be arranged the third year
Delivery of a batch of 1st generation MOF (Fe-BTC) for shaping development (WP5) – 0.5kgPhysical proof that sample has been prepared incl main characterization data
Delivery of shaped productsProof that shaped products have been produced and their main characteristica are provided
Delivery of up to 10kg of NPMs by spray-dryingProof that the needed amount of NPMs have been påroduced and its characteristica are provided
Delivery of first samples for testing (WP1), post-synthesis treatments (WP2) and shaping development (WP5) – 0.1g-1kg scaleProof that sample has been prepared incl main characterisation data
Delivery of up to 5 kg MOFs by batch synthesisProof that the needed amount of MOFs have been produced by batch synthesis and the product characteristica is provided
Delivery of first samples of porous aluminosilicate for testing in WP1Proof that samples have been prapered and delivered for further processing
Delivery of up to 100kg of NPMs by mecanosynthesisProof that the needed amout of NPMs have been produced at the main characteristica is provided
Delivery of HKUST-1 for shaping development in WP5 – 0,5kg scaleProof that sample has been prepared incl main characteristica.
Delivery of up to 0.5kg MOFs by batch synthesisProof that the needed amout of MOFs have been produced and its characteristics are provided
A report describing briefly the performance of all selected NPMs for the four applications chosen
Proof that a prototype integrating the methane storage cylinder containg MOF is provided
Communication tools have been established and communicated
Pubblicazioni
Autori:
Marta Rubio-Martinez, Ceren Avci-Camur, Aaron W. Thornton, Inhar Imaz, Daniel Maspoch, Matthew R. Hill
Pubblicato in:
Chemical Society Reviews, Numero 46/11, 2017, Pagina/e 3453-3480, ISSN 0306-0012
Editore:
Royal Society of Chemistry
DOI:
10.1039/c7cs00109f
Autori:
Giulia P. M. Bignami, Zachary H. Davis, Daniel M. Dawson, Samuel A. Morris, Samantha E. Russell, David McKay, Richard E. Parke, Dinu Iuga, Russell E. Morris, Sharon E. Ashbrook
Pubblicato in:
Chemical Science, Numero 9/4, 2018, Pagina/e 850-859, ISSN 2041-6520
Editore:
Royal Society of Chemistry
DOI:
10.1039/C7SC04649A
Autori:
S. Hindocha, S. Poulston
Pubblicato in:
Faraday Discussions, Numero 201, 2017, Pagina/e 113-125, ISSN 1359-6640
Editore:
Royal Society of Chemistry
DOI:
10.1039/c7fd00090a
Autori:
Francis Meunier
Pubblicato in:
Science, Numero 358/6366, 2017, Pagina/e eaao0361, ISSN 0036-8075
Editore:
American Association for the Advancement of Science
DOI:
10.1126/science.aao0361
Autori:
Yoldes Khabzina, David Farrusseng
Pubblicato in:
Microporous and Mesoporous Materials, Numero 265, 2018, Pagina/e 143-148, ISSN 1387-1811
Editore:
Elsevier BV
DOI:
10.1016/j.micromeso.2018.02.011
Autori:
Yoldes Khabzina, Jeremy Dhainaut, Matthias Ahlhelm, Hans-Juergen Richter, Helge Reinsch, Norbert Stock, David Farrusseng
Pubblicato in:
Industrial & Engineering Chemistry Research, Numero 57/24, 2018, Pagina/e 8200-8208, ISSN 0888-5885
Editore:
American Chemical Society
DOI:
10.1021/acs.iecr.8b00808
Autori:
Ceren Avci-Camur, Javier Troyano, Javier Pérez-Carvajal, Alexandre Legrand, David Farrusseng, Inhar Imaz, Daniel Maspoch
Pubblicato in:
Green Chemistry, Numero 20/4, 2018, Pagina/e 873-878, ISSN 1463-9262
Editore:
Royal Society of Chemistry
DOI:
10.1039/c7gc03132g
Autori:
Cesare Atzori, Greig C. Shearer, Lorenzo Maschio, Bartolomeo Civalleri, Francesca Bonino, Carlo Lamberti, Stian Svelle, Karl Petter Lillerud, Silvia Bordiga
Pubblicato in:
The Journal of Physical Chemistry C, 2017, ISSN 1932-7447
Editore:
American Chemical Society
DOI:
10.1021/acs.jpcc.7b00483
Autori:
Alexandre Legrand, Anton Pastushenko, Vladimir Lysenko, Alain Geloen, Elsje Alessandra Quadrelli, Jerome Canivet, David Farrusseng
Pubblicato in:
ChemNanoMat, Numero 2/9, 2016, Pagina/e 866-872, ISSN 2199-692X
Editore:
Wiley-VCH Verlag GmbH & Co
DOI:
10.1002/cnma.201600124
Autori:
J. Dhainaut, C. Avci-Camur, J. Troyano, A. Legrand, J. Canivet, I. Imaz, D. Maspoch, H. Reinsch, D. Farrusseng
Pubblicato in:
CrystEngComm, 2017, ISSN 1466-8033
Editore:
Royal Society of Chemistry
DOI:
10.1039/C7CE00338B
Autori:
Luis Garzón-Tovar, Sabina Rodríguez-Hermida, Inhar Imaz and Daniel Maspoch
Pubblicato in:
J. Am. Chem. soc, 2017, ISSN 0002-7863
Editore:
American Chemical Society
DOI:
10.1021/jacs.6b11240
Autori:
Luis Garzón-Tovar, Javier Pérez-Carvajal, Inhar Imaz, Daniel Maspoch
Pubblicato in:
Advanced Functional Materials, Numero 27/21, 2017, Pagina/e 1606424, ISSN 1616-301X
Editore:
John Wiley & Sons Ltd.
DOI:
10.1002/adfm.201606424
Autori:
Vincent Guillerm, Luis Garzón-Tovar, Amirali Yazdi, Inhar Imaz, Jordi Juanhuix, Daniel Maspoch
Pubblicato in:
Chemistry - A European Journal, Numero 23/28, 2017, Pagina/e 6829-6835, ISSN 0947-6539
Editore:
John Wiley & Sons Ltd.
DOI:
10.1002/chem.201605507
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