Photocatalytic Generation of CarbAnions for Organic Synthesis

Informazioni relative al progetto

PHAROS

ID dell’accordo di sovvenzione: 741623

DOI 10.3030/741623

Progetto chiuso

Data della firma CE 2 Maggio 2017

Data di avvio 1 Settembre 2017

Data di completamento 31 Agosto 2022

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale € 2 458 200,00

Contributo UE € 2 458 200,00

Coordinato da

UNIVERSITAET REGENSBURG
Germany

Pubblicazioni

Peer reviewed articles (26)

Redox-Neutral Photocatalytic C-H Carboxylation of Arenes and Styrenes with CO2

Autori: Matthias Schmalzbauer, Thomas D. Svejstrup, Florian Fricke, Peter Brandt, Magnus J. Johansson, Giulia Bergonzini, Burkhard Koenig
Pubblicato in: Chem, Numero 6, 2020, Pagina/e 2658–2672, ISSN 2451-9294
Editore: Elsevier
DOI: 10.1016/j.chempr.2020.08.022

Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors

Autori: Thomas D. Svejstrup, Anamitra Chatterjee, Denis Schekin, Thomas Wagner, Julia Zach, Magnus J. Johansson, Giulia Bergonzini, Burkhard König
Pubblicato in: ChemPhotoChem, Numero 5, 2021, Pagina/e 808 – 814, ISSN 2367-0932
Editore: Wiley
DOI: 10.1002/cptc.202100059

Deazaflavin reductive photocatalysis involves excited semiquinone radicals

Autori: Andreas Graml, Tomáš Neveselý, Roger Jan Kutta, Radek Cibulka, Burkhard König
Pubblicato in: Nature Communications, Numero 11/1, 2020, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-020-16909-y

Mizoroki–Heck type reactions and synthesis of 1,4-dicarbonyl compounds by heterogeneous organic semiconductor photocatalysis

Autori: Jagadish Khamrai, Saikat Das, Aleksandr Savateev, Markus Antonietti, Burkhard König
Pubblicato in: Green Chem, Numero 23, 2021, Pagina/e 2017 - 2024, ISSN 1463-9262
Editore: Royal Society of Chemistry
DOI: 10.1039/d0gc03792c

Visible‐Light‐Promoted Metal‐Free Synthesis of (Hetero)Aromatic Nitriles from C(sp 3 )−H Bonds**

Autori: Kathiravan Murugesan, Karsten Donabauer, Burkhard König
Pubblicato in: Angewandte Chemie, Numero 133/5, 2021, Pagina/e 2469-2475, ISSN 0044-8249
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202011815

Photo-Induced Thiolate Catalytic Activation of Inert Caryl-Hetero Bondsfor Radical Borylation

Autori: Shun Wang, Hua Wang, Burkhard Koenig
Pubblicato in: Chem, Numero 7, 2021, Pagina/e 1653-1665, ISSN 2451-9294
Editore: Cell Press
DOI: 10.1016/j.chempr.2021.04.016

Photocatalytic synthesis of tetra-substituted furans promoted by carbon dioxide†

Autori: Ya-Ming Tian, Huaiju Wang, Ritu, Burkhard Koenig
Pubblicato in: Chemical Science, Numero 13, 2022, Pagina/e 241, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d1sc06403g

Photoinitiated Carbonyl-Metathesis: Deoxygenative Reductive Olefination of Aromatic Aldehydes via Photoredox Catalysis

Autori: Shun Wang, Lokesh Nanjundappa, Johnny Hioe, Ruth Maria Gschwind, Burkhard Koenig
Pubblicato in: Chemical Science, 2019, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c9sc00711c

Photocatalytic Barbier reaction – visible-light induced allylation and benzylation of aldehydes and ketones

Autori: Anna Lucia Berger, Karsten Donabauer, Burkhard König
Pubblicato in: Chemical Science, Numero 9/36, 2018, Pagina/e 7230-7235, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c8sc02038h

Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

Autori: Veera Reddy Yatham, Peter Bellotti, Burkhard König
Pubblicato in: Chemical Communications, Numero 55/24, 2019, Pagina/e 3489-3492, ISSN 1359-7345
Editore: Royal Society of Chemistry
DOI: 10.1039/c9cc00492k

Controllable Isomerization of Alkenes by Dual Visible-Light-Cobalt Catalysis

Autori: Qing-Yuan Meng, Tobias Schirmer, Kousuke Katou, Burkhard König
Pubblicato in: Angewandte Chemie International Edition, 2019, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201900849

Photocarboxylation of Benzylic C–H Bonds

Autori: Qing-Yuan Meng, Tobias E. Schirmer, Anna Lucia Berger, Karsten Donabauer, Burkhard König
Pubblicato in: Journal of the American Chemical Society, Numero 141/29, 2019, Pagina/e 11393-11397, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.9b05360

Photocatalytic carbanion generation – benzylation of aliphatic aldehydes to secondary alcohols

Autori: Karsten Donabauer, Mitasree Maity, Anna Lucia Berger, Gregory S. Huff, Stefano Crespi, Burkhard König
Pubblicato in: Chemical Science, Numero 10/19, 2019, Pagina/e 5162-5166, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c9sc01356c

Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes

Autori: Indrajit Ghosh, Jagadish Khamrai, Aleksandr Savateev, Nikita Shlapakov, Markus Antonietti, Burkhard König
Pubblicato in: Science, Numero 365/6451, 2019, Pagina/e 360-366, ISSN 0036-8075
Editore: American Association for the Advancement of Science
DOI: 10.1126/science.aaw3254

Birch‐Type Photoreduction of Arenes and Heteroarenes by Sensitized Electron Transfer

Autori: Anamitra Chatterjee, Burkhard König
Pubblicato in: Angewandte Chemie International Edition, Numero 58/40, 2019, Pagina/e 14289-14294, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201905485

Photochemical Functionalization of Helicenes

Autori: Martin Jakubec, Indrajit Ghosh, Jan Storch, Burkhard König
Pubblicato in: Chemistry – A European Journal, Numero 26/2, 2019, Pagina/e 543-547, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201904169

Photocatalytic carbanion generation from C–H bonds – reductant free Barbier/Grignard-type reactions

Autori: Anna Lucia Berger, Karsten Donabauer, Burkhard König
Pubblicato in: Chemical Science, Numero 10/48, 2019, Pagina/e 10991-10996, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/c9sc04987h

Synthetic Photoelectrochemistry

Autori: Joshua P. Barham, Burkhard König
Pubblicato in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201913767

Photocatalytic Synthesis of Polycyclic Indolones

Autori: Tanguy Saget, Burkhard König
Pubblicato in: Chemistry - A European Journal, 2020, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001324

Umpolung Difunctionalization of Carbonyls via Visible-Light Photoredox Catalytic Radical-Carbanion Relay

Autori: Shun Wang, Bei-Yi Cheng, Matea Sršen, Burkhard König
Pubblicato in: Journal of the American Chemical Society, 2020, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.0c00629

Excited State Anions in Organic Transformations

Autori: Matthias Schmalzbauer, Michela Marcon, and Burkhard Koenig
Pubblicato in: Angewandte Chemie, Numero 60, 2021, Pagina/e 6270–6292, ISSN 1521-3757
Editore: Wiley-VCh
DOI: 10.1002/anie.202009288

Photocatalytic (Het)arylation of C(sp3)−H Bonds with Carbon Nitride

Autori: Saikat Das, Kathiravan Murugesan, Gonzalo J. Villegas Rodríguez, Jaspreet Kaur, Joshua P. Barham, Aleksandr Savateev, Markus Antonietti, Burkhard König
Pubblicato in: ACS catalysis, Numero 11, 2021, Pagina/e 1593−1603, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.0c05694

Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C−C Bond Formations

Autori: Karsten Donabauer, Burkhard Koenig
Pubblicato in: Acc. Chem. Res., Numero 54, 2021, Pagina/e 242−252, ISSN 1520-4898
Editore: ACS
DOI: 10.1021/acs.accounts.0c00620

N -Arylation of NH -Sulfoximines via Dual Nickel Photocatalysis

Autori: Alexander Wimmer, Burkhard König
Pubblicato in: Organic Letters, Numero 21/8, 2019, Pagina/e 2740-2744, ISSN 1523-7060
Editore: American Chemical Society
DOI: 10.1021/acs.orglett.9b00698

Visible-Light-Promoted Metal-Free Synthesis of (Hetero)AromaticNitriles from C(sp3)-H Bonds

Autori: Kathiravan Murugesan, Karsten Donabauer, Burkhard Koenig
Pubblicato in: Angewandte Chemie, Numero 60, 2021, Pagina/e 2439-2445, ISSN 1521-3773
Editore: Wiley
DOI: 10.1002/anie.202011815

Photocatalytic Reductive Radical‐Polar Crossover for a Base‐Free Corey–Seebach Reaction

Autori: Karsten Donabauer, Kathiravan Murugesan, Urša Rozman, Stefano Crespi, Burkhard König
Pubblicato in: Chemistry – A European Journal, 2020, ISSN 0947-6539
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202003000