in-built Triggered Enzymes to Recycle Multi-layers: an INnovation for USes in plastic-packaging

Project Information

TERMINUS

Grant agreement ID: 814400

DOI 10.3030/814400

Project closed

EC signature date 12 December 2018

Start date 1 January 2019

End date 31 July 2023

Funded under

• INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials

Total cost € 5 737 013,75

EU contribution € 5 737 013,75

Coordinated by

CLERMONT AUVERGNE INP
France

Deliverables

Websites, patent fillings, videos etc. (4)

Industrial workshop organisation

Industrial workshop organisation dedicated to industrials

Scientific workshop organisation

Scientific workshop organisation for scientists and academics

Scientific and industrial papers

Scientif and industrial papers describing TERMINUS results

PEDR

PEDR including Project Identity Set [logo, social media accounts, templates, brochure] and website

Documents, reports (3)

Final technology integration action plan

Technology integration action plan final version based on last results to facilitate technology adoption by industrials

Report on regulatory aspects and food contact safety

Report on regulatory aspects and food contact safety to be published to Promote TERMINUS results

Initial technology integration action plan

Technology integration action plan first version based on first results to facilitate technology adoption by industrials

Other (1)

Legislative review and recommendations report

Legislative review and recommendations report to be taken into account by industrials for the development of packaging, taking into account TERMINUS specifications

Publications

Conference proceedings (17)

Induction of viscosity increase during polyglycol addition to isocyanates

Author(s): Nemaniutė, Paulina; Bražinskienė, Dalia; Asadauskas, Svajus Joseph
Published in: Proceedings of 64th International Conference for Students of Physics and Natural Sciences (Open Readings 2022), Issue 2021, 2021, Page(s) 400
Publisher: Vilnius University
DOI: 10.5281/zenodo.4778505

Influence of ester diluents and chain extension on polyurethane viscosities

Author(s): Asadauskas, Svajus Joseph; Mačiulytė, Sandra; Bražinskienė, Dalia; Matijošius, Tadas; Nemaniute, Paulina
Published in: Proceedings of 21st International Conference Advanced Materials and Technologies 2020, Issue 2020, 2020
Publisher: Kaunas University of Technology
DOI: 10.5281/zenodo.4064005

Bio-derived feedstocks for natural deep eutectic solvents

Author(s): Dalia Bražinskienė; Audrė Kalinauskaitė; Svajus Joseph Asadauskas
Published in: Proceedings of 32nd Annual Meeting of Association for Advancement of Industrial Crops, Issue 2021, 2021, Page(s) 38
Publisher: University of Bologna
DOI: 10.5281/zenodo.6359497

Influence of Layered Double Hydroxides on Polyaddition of Aromatic Isocyanate and Macrodiol

Author(s): Gytautė Sirgėdaitė; Paulina Nemaniutė; Dalia Bražinskienė; Svajus Joseph Asadauskas
Published in: Proceedings of 65th International Conference for Students of Physics and Natural Sciences (Open Readings 2022), Issue 1, 2022, Page(s) 409
Publisher: Vilnius University
DOI: 10.5281/zenodo.6359681

Effects of isocyanate addition on viscosity of ester-based polyurethanes

Author(s): Nemaniutė, Paulina; Matijošius, Tadas; Bražinskienė, Dalia; Asadauskas, Svajus Joseph
Published in: Issue 1, 2022
Publisher: "24th International Conference-School ""Advanced Materials and Technologies"" (AMT-2022)"
DOI: 10.5281/zenodo.7146381

Multilayers packaging recycling: the Terminus strategy

Author(s): Romano, Angela; Totaro, Grazia; Celli, Annamaria; Gioia, Claudio; Raddadi, Noura; Zanaroli, Giulio; Sisti, Laura
Published in: Issue 4, 2020
Publisher: Ecomondo The Green Technology Expo (Ecomondo 2020)
DOI: 10.5281/zenodo.6810657

Monitoring of Polyurethane Penetration into Alumina Coating by Raman Spectroscopy

Author(s): Matijošius, Tadas; Ignatjev, Ilja; Asadauskas, Svajus J.
Published in: Issue 5, 2023
Publisher: 18th International Conference on Electroanalysis (ESEAC 2022)
DOI: 10.5281/zenodo.8204883

Viscosity Variation During Addition of Polyglycols to Trifunctional Isocyanate

Author(s): Paulina Nemaniutė; Marijus Jurkūnas; Dalia Bražinskienė; Svajus Joseph Asadauskas
Published in: Proceedings of 65th International Conference for Students of Physics and Natural Sciences (Open Readings 2022), Issue 2022, 2022, Page(s) 424
Publisher: Vilnius University
DOI: 10.5281/zenodo.6359696

Viscosity Variation During Addition of Ester and Ether Macrodiols to Isocyanates

Author(s): Paulina Nemaniutė; Marijus Jurkūnas; Dalia Bražinskienė; Svajus Joseph Asadauskas
Published in: Proceedings of 22nd Conf. Advanced Materials and Technologies, Issue 2021, 2021, Page(s) 175, ISSN 2669-1930
Publisher: Kaunas University of Technology
DOI: 10.5281/zenodo.6359427

Tendencies of Solid Phase Formation in Deep Eutectic Solvents of Betaine and Xylitol

Author(s): Kalinauskaitė, Audrė; Bražinskienė, Dalia; Asadauskas, Svajus
Published in: Issue 20, 2021
Publisher: "23rd International Conference-School ""Advanced Materials and Technologies"" (AMT-2021)"
DOI: 10.5281/zenodo.5494746

Influence of Aliphatic Moieties in Diisocyanates on Chain Extension Kinetics of Adipate Macrodiols

Author(s): Mačiulytė, Sandra; Strakšys, Antanas; Asadauskas, Svajus Joseph
Published in: Proceedings of Baltic Polymer Symposium 2019, Issue 2019, 2019, Page(s) 40
Publisher: Baltic Polymer Symposium
DOI: 10.5281/zenodo.3813463

Circular Economy of plastic multilayer packaging: H2020 Terminus project

Author(s): Vincent Verney
Published in: Chemistry meets Industry and Society A creative showcase conference, 2019, Page(s) 285
Publisher: Società Chimica Italiana
DOI: 10.5281/zenodo.3824081

Chain extension of caprolactone and ethylene glycol macrodiols into hydroxyl-terminated polyurethanes

Author(s): Asadauskas, Svajus Joseph; Mačiulytė, Sandra; Strakšys, Antanas; Bėkiš, Julija
Published in: Issue 2, 2019
Publisher: LITHUANIAN CHEMISTS CONFERENCE CHEMISTRY AND CHEMICAL TECHNOLOGY
DOI: 10.5281/zenodo.3871589

Short-term and long-term volatilities of films from polyol ester and ether-based oils of various molecular weights

Author(s): Asadauskas, Svajus Joseph; Bražinskienė, Dalia; Grigucevičienė, Asta
Published in: Proceedings of 10th International Conference Balttrib, Issue 2019, 2019, Page(s) 54-57, ISSN 2424-5089
Publisher: 10th International Conference BALTTRIB’2019
DOI: 10.5281/zenodo.3871587

Additive effects on curing ester-based degradable polyurethane adhesives

Author(s): Mačiulytė, Sandra; Nemaniutė, Paulina; Bražinskienė, Dalia; Eicher-Lorka, Olegas; Asadauskas, Svajus Joseph
Published in: Issue 3, 2022
Publisher: 8th European Bioremediation Conference (EBC-VIII)
DOI: 10.5281/zenodo.6673073

New strategy for Multilayers packaging recycling

Author(s): Rosato Antonella; Grazia, Totaro; Annamaria, Celli; Noura, Raddadi; Giulio, Zanaroli; Laura, Sisti
Published in: Issue 2, 2020
Publisher: Ecomondo
DOI: 10.5281/zenodo.4247372

Enzymatic degradation of a commercial bio-based polyester and evaluation of the mechanism involved

Author(s): Angela, Romano; Rosato Antonella; Grazia, Totaro; Annamaria, Celli; Giulio, Zanaroli; Laura, Sisti
Published in: Issue 1, 2020
Publisher: European Bioplastics
DOI: 10.5281/zenodo.4327388

Other (14)

Terminus WP4 Enzyme immobilization, protection, and triggering. Task 4.1 Task 4.2 Experimental data - Hydrolytic enzyme immobilization and triggering

Author(s): Grazia Totaro, Angela Romano, Antonella Rosato, Giulio Zanaroli, Annamaria Celli, Laura Sisti
Published in: Dataset, 2021
Publisher: Zenodo
DOI: 10.5281/zenodo.5006115

Enzymatic degradation of the most common aliphatic biopolyesters

Author(s): Romano, Angela; Rosato, Antonella; Totaro, Grazia; Celli, Annamaria; Zanaroli, Giulio; Sisti, Laura
Published in: Proceedings of European Polymer Congress EPF 2022, 2022
Publisher: European Polymer Congress EPF 2022
DOI: 10.5281/zenodo.6810654

THE POWER OF NADES - BOOSTING ENZYME STABILITY TOWARDS THERMAL DEGRADATION

Author(s): Varriale, Simona; Delorme, Astrid E.; Jean-Michel Andanson; Devemy, Julien; Malfreyt, Patrice; Verney, Vincent; Pezzella, Cinzia
Published in: 2022
Publisher: European Bioremediation Conference EBC-VIII
DOI: 10.5281/zenodo.7188432

Thermally protected enzyme for degradable on-demand polymers

Author(s): Romano, Angela; Rosato, Antonella; Totaro, Grazia; Zanaroli, Giulio; Celli, Annamaria; Sisti Laura
Published in: Proceedings of Bio-based Polymers at the Forefront of Innovation in Materials Science, 2023
Publisher: Bio-based Polymers at the Forefront of Innovation in Materials Science
DOI: 10.5281/zenodo.7828613

Efficient enzymatic degradation of poly(ε-caprolactone) by a commercial lipase

Author(s): Romano, Angela; Rosato, Antonella; Totaro, Grazia; Zanaroli, Giulio; Celli, Annamaria; Sisti, Laura
Published in: Issue 2, 2021
Publisher: Ecomondo The Green Technology Expo 2021
DOI: 10.5281/zenodo.5747072

Increasing recyclability of multi-layer plastic packaging with TERMINUS

Author(s): Vincent VERNEY, Nina KNEZIC
Published in: 2020
Publisher: TERMINUS-H2020
DOI: 10.5281/zenodo.3693857

TERMINUS - Newsletter April 2020

Author(s): KNEZIC, Nina
Published in: Issue 2, 2020
Publisher: TERMINUS
DOI: 10.5281/zenodo.3822085

Recycling by-design of plastics through thermally protected enzymes

Author(s): Romano, Angela; Rosato, Antonella; Totaro, Grazia; Zanaroli, Giulio; Celli, Annamaria; Sisti, Laura
Published in: Proceedings of XIII Congresso Nazionale AicIng 2023, 2023
Publisher: XIII Congresso Nazionale AicIng 2023
DOI: 10.5281/zenodo.8063810

Enhancement of laccases thermostability in Betaine based Natural Deep Eutectic Solvents

Author(s): Simona Varriale; Astrid E. Delorme; Jean-Michel Andanson; Vincent Verney; Cinzia Pezzella
Published in: 2021
Publisher: 3rd Aachen Protein Engineering Symposium
DOI: 10.5281/zenodo.7189092

Multilayers packaging recycling: the Terminus strategy

Author(s): Romano, Angela; Totaro, Grazia; Celli, Annamaria; Gioia, Claudio; Raddadi, Noura; Zanaroli, Giulio; Sisti, Laura
Published in: Proceedings of European Polymer Congress EPF 2022, 2022
Publisher: European Polymer Congress EPF 2022
DOI: 10.5281/zenodo.6810658

Enzymatic degradation of polyesters

Author(s): Totaro, Grazia; Rosato, Antonella; Romano, Angela; Zanaroli Giulio; Celli, Annamaria; Sisti Laura
Published in: Proceedings of X International Conference Times of Polymers and Composites (TOP Conference 2021), 2021
Publisher: X International Conference Times of Polymers and Composites (TOP Conference 2021)
DOI: 10.5281/zenodo.5746967

Enzymatic degradation of the most common aliphatic polyesters

Author(s): Antonella, Rosato; Angela, Romano; Grazia, Totaro; Annamaria, Celli; Fabio Fava; Laura, Sisti, Giulio Zanaroli
Published in: Proceedings of VII European Bioremediation Conference EBC-VIII 2022, 2022
Publisher: VII European Bioremediation Conference EBC-VIII 2022

The power of NADES: Boosting enzyme stability towards thermal degradation

Author(s): Simona Varriale; Astrid E. Delorme; Jean-Michel Andanson; Julien Devemy; Patrice Malfreyt; Vincent Verney; Cinzia Pezzella
Published in: 2022
Publisher: Oxizymes Siena
DOI: 10.5281/zenodo.7186465

Studio del meccanismo di degradazione enzimatica di poliesteri commerciali

Author(s): Romano, Angela; Rosato, Antonella; Totaro, Grazia; Celli, Annamaria; Sisti, Laura; Zanaroli, Giulio
Published in: Proceedings of XII National Congress AicIng 2021, 2021
Publisher: XII National Congress AicIng 2021
DOI: 10.5281/zenodo.5747099

Peer reviewed articles (7)

Enhancing the Thermostability of Engineered Laccases in Aqueous Betaine-Based Natural Deep Eutectic Solvents

Author(s): Simona Varriale; Astrid E. Delorme; Jean-Michel Andanson; Julien Devemy; Patrice Malfreyt; Vincent Verney; Cinzia Pezzella
Published in: ACS Sustainable Chemistry and Engineering, Issue 1, 2022, ISSN 2168-0485
Publisher: American Chemical Society
DOI: 10.1021/acssuschemeng.1c07104

Triggering of Polymer-Degrading Enzymes from Layered Double Hydroxides for Recycling Strategies

Author(s): Angela Romano, Antonella Rosato, Stefano Bianchi, Giulio Zanaroli, Annamaria Celli, Grazia Totaro, Laura Sisti
Published in: International Journal of Molecular Sciences, 2023, ISSN 1661-6596
Publisher: MDPI
DOI: 10.3390/ijms24010831

Recycling by-design of plastic through formulation with thermally protected enzymes in layered doble hydroxide structures

Author(s): Angela Romano, Antonella Rosato, Grazia Totaro, Giulio Zanaroli, Annamaria Celli
Published in: Journal of Cleaner Production, 2023, ISSN 0959-6526
Publisher: Elsevier BV
DOI: 10.1016/j.jclepro.2022.135517

Natural deep eutectic solvents as thermostabilizer for Humicola insolens cutinase

Author(s): Romano, Angela; Varriale, Simona; Pezzella, Cinzia; Totaro, Grazia; Andanson, Jean-Michel; Verney, Vincent; Sisti, Laura
Published in: New Biotechnology, 2023, ISSN 1871-6784
Publisher: Elsevier BV
DOI: 10.1016/j.nbt.2023.05.006

Improving laccase thermostability with aqueous natural deep eutectic solvents

Author(s): Astrid E. Delorme, Jean-Michel Andanson, Vincent Verney
Published in: International Journal of Biological Macromolecules, Issue 163, 2020, Page(s) 919-926, ISSN 0141-8130
Publisher: Elsevier BV
DOI: 10.1016/j.ijbiomac.2020.07.022

Enhancement of Gas Barrier Properties and Durability of Poly(butylene succinate-co-butylene adipate)-Based Nanocomposites for Food Packaging Applications

Author(s): Astrid E. Delorme; Tanja Radusin; Petri Myllytie; Vincent Verney; Haroutioun Askanian
Published in: "Nanomaterials, 2022, 12 (6), pp.978. ⟨10.3390/nano12060978⟩", Issue 2, 2022, ISSN 2079-4991
Publisher: Nanomaterials
DOI: 10.3390/nano12060978

Enzymatic Degradation of the Most Common Aliphatic Bio-Polyesters and Evaluation of the Mechanisms Involved: An Extended Study

Author(s): Rosato, Antonella; Romano, Angela; Totaro, Grazia; Celli, Annamaria; Fava, Fabio; Zanaroli, Giulio; Sisti, Laura
Published in: Polymers, 2022, ISSN 2073-4360
Publisher: MDPI
DOI: 10.3390/polym14091850