GHz nanoscale electrical and dielectric measurements of the solid-electrolyte interface and applications in the battery manufacturing line

Project Information

NanoBat

Grant agreement ID: 861962

DOI 10.3030/861962

Project closed

EC signature date 12 March 2020

Start date 1 April 2020

End date 31 March 2023

Funded under

• INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials

Total cost € 4 966 912,50

EU contribution € 4 966 912,50

Coordinated by

KEYSIGHT TECHNOLOGIES GMBH
Austria

Deliverables

Demonstrators, pilots, prototypes (4)

SDC setup under inert atmosphere

Droplet cell screening setup developed under inert atmosphere and tested for SEI defects by combining mediated cyclicvoltammetry and ACmeasurements up to 02 MHz performing automatically with 500 electrochemical measurements with only 1h working efforts IMDEA M22

SMM and BBIM demonstrator setup

GHzSMM and wideband BBIM demonstrator setups developed capable of operating the isolated and shielded nanoscale probes in LIB electrolytes and under inert gas atmosphere in a frequency range of 120 GHz with 20 nanometre lateral resolution 1 nm vertical resolution and 05 aF capacitive resolution JKU M28

Demonstration of scanning 200x200um area in less than 20 s

Device chip with interferometer readout for scanning a 200x200 pixel and 200x200um area in less than 20 seconds on an electrochemical halfcell with SEI layer formation METAS M34

SECM setup under inert atmosphere

SECM setup developed under inert atmosphere for ion and electronconductivity defects of the SEI layer with m lateral resolution by combination of feedback mode and ACmode operating up to 1 MHz RUB M12

Websites, patent fillings, videos etc. (3)

Working open innovation environment

Working open innovation environment including registration mechanism access systems for different confidentiality levels and stakeholder groups as well as Zenodo open data community METAS M6

Public project website, Social media accounts

Public project website and social media accounts established on LinkedIn and Twitter. (EURICE, M4)

Audio Visual Material

Audio Visual Material provided EURICE M18

Documents, reports (5)

Liaison activities with external stakeholders – 1st report

Liaison activities with external stakeholders 1st report EURICE M18

Report on the interlaboratory measurement comparison

Report on the interlaboratory measurement comparison and roundrobin report with reference cells and artefacts for short and open circuits and resistance METAS M32

Evidence of submitted CMC entry and SOPs

CMC submitted and SOPs on LIBEIS SMM measurements in liquids mediator enhanced coulometry and SDM established and feedback included from stakeholder community METAS M30

Communication Toolkit and Cooperate Design

Corporate design and communication toolkit established EURICE M6

Report on risk assessment

Report on risk assessment Risk will be regularly checked assessed and reevaluated during the course of the project The report will comprise descriptions and contingency plans KEYS M12

Open Research Data Pilot (3)

Updated Data Management Plan, FAIR data, data security

Data Management Plan addressing the following points which data is stored FAIR data data security and ethical aspects METAS M6 updated M18 and M30

Final Data Management Plan, FAIR data, data security

Data Management Plan addressing the following points which data is stored FAIR data data security and ethical aspects METAS M6 updated M18 and M30

Data Management Plan, FAIR data, data security

Data Management Plan addressing the following points which data is stored FAIR data data security and ethical aspects METAS M6 updated M18 and M30

Other (1)

Simulation toolbox for coupled models on the open platform

Open platform simulation toolbox for coupled GHzthermal models with 6 examples representative of GHznanoscale battery materials and halfcells QWED M34

Publications

Peer reviewed articles (19)

Measurement Uncertainty in Battery Electrochemical Impedance Spectroscopy

Author(s): Moradpour, Amin; Kasper, Manuel; Hoffmann, Johannes; Kienberger, Ferry
Published in: IEEE Transactions on Instrumentation and Measurement, Issue 71, 2023, ISSN 1557-9662
Publisher: IEEE
DOI: 10.1109/TIM.2022.3198466

Quantitative Cell Classification Based on Calibrated Impedance Spectroscopy and Metrological Uncertainty

Author(s): Moradpour, Amin; Kasper, Manuel; Kienberger, Ferry
Published in: Batteries & Supercaps, 2023, ISSN 2566-6223
Publisher: Chemistry Europe, Wiley-VCH
DOI: 10.1002/batt.202200524

Nanoscale electrochemical charge transfer kinetics investigated by electrochemical scanning microwave microscopy

Author(s): Awadein, Mohamed; Sparey, Maxwell; Grall, Simon; Kienberger, Ferry; Clement, Nicolas; Gramse, Georg
Published in: Nanoscale Advances, Issue 3, 2023, ISSN 2516-0230
Publisher: Royal Society of Chemistry
DOI: 10.1039/D2NA00671E

New Technique for Probing the Protecting Character of the Solid Electrolyte Interphase as a Critical but Elusive Property for Pursuing Long Cycle Life Lithium-Ion Batteries

Author(s): Enrique Garcia-Quismondo, Sandra Alvarez-Conde, Guzmán Garcia, Jesús I. Medina-Santos, Jesús Palma, and Edgar Ventosa
Published in: Applied Materials & Interfaces, Issue Volume 14, issue 38, 2022, ISSN 1944-8252
Publisher: ACS Publications
DOI: 10.1021/acsami.2c11992

Intelligente elektrochemische Rasterzellmikroskopie für den Nachweis schneller Li-Ionen-Speicherung und Dynamik in TiO2- Nanopartikeln

Author(s): Batsa Tetteh, Emmanuel; Valavanis, Dimitrios; Daviddi, Enrico; Xu, Xiangdong; Santana Santos, Carla; Ventosa, Edgar; Martín-Yerga, Daniel; Schuhmann, Wolfgang; Unwin, Patrick R.
Published in: Angewandte Chemie, Issue 135, 2023, Page(s) e202214493, ISSN 0044-8249
Publisher: Wiley VCH
DOI: 10.1002/ange.202214493

Accelerated Electrochemical Investigation of Li Plating Efficiency as Key Parameter for Li Metal Batteries Utilizing a Scanning Droplet Cell

Author(s): Stefan Dieckhöfer, Wolfgang Schuhmann, Edgar Ventosa
Published in: ChemElectroChem, Issue 8/16, 2021, Page(s) 3143-3149, ISSN 2196-0216
Publisher: Wiley-VCH
DOI: 10.1002/celc.202100733

Correlative Electrochemical Microscopy for the Elucidation of the Local Ionic and Electronic Properties of the Solid Electrolyte Interphase in Li-Ion Batteries

Author(s): Santos, Carla S.; Botz, Alexander; Bandarenka, Aliaksandr S.; Ventosa, Edgar; Schuhmann, Wolfgang
Published in: Angewandte Chemie International Edition, Issue 1, 2022, ISSN 0570-0833
Publisher: Wiley-VCH GmbH
DOI: 10.1002/anie.202202744

Attoampere Nanoelectrochemistry

Author(s): Simon Grall, Ivan Alić, Eleonora Pavoni, Mohamed Awadein, Teruo Fujii, Stefan Müllegger, Marco Farina, Nicolas Clément, Georg Gramse
Published in: Small, Issue 17/29, 2021, Page(s) 2101253, ISSN 1613-6810
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/smll.202101253

Advanced Electrochemical Impedance Spectroscopy of Industrial Ni-Cd Batteries

Author(s): Al-Zubaidi R-Smith, Nawfal; Kasper, Manuel; Kumar, Peeyush; Nilsson, Daniel; Marlid, Björn; Kienberger, Ferry
Published in: Batteries, Issue Volume 8, issue 6, 2022, ISSN 2313-0105
Publisher: MDPI
DOI: 10.3390/batteries8060050

Why nanoelectrochemistry is necessary in battery research?

Author(s): Edgar Ventosa
Published in: Current Opinion in Electrochemistry, Issue 25, 2021, Page(s) 100635, ISSN 2451-9103
Publisher: Elsevier B.V.
DOI: 10.1016/j.coelec.2020.09.002

Assessment of lithium ion battery ageing by combined impedance spectroscopy, functional microscopy and finite element modelling

Author(s): Nawfal Al-Zubaidi R-Smith, Michael Leitner, Ivan Alic, David Toth, Manuel Kasper, Martina Romio, Yuri Surace, Marcus Jahn, Ferry Kienberger, Andreas Ebner, Georg Gramse
Published in: Journal of Power Sources, Issue 512, 2021, Page(s) 230459, ISSN 0378-7753
Publisher: Elsevier BV
DOI: 10.1016/j.jpowsour.2021.230459

Operando Scanning Electrochemical Probe Microscopy during Electrocatalysis

Author(s): Santana Santos, Carla; Jaato, Bright Nsolebna; Sanjuán, Ignacio; Schuhmann, Wolfgang; Andronescu, Corina
Published in: ACS - Chemical Reviews, Issue 123, 2023, Page(s) 4972–5019, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.2c00766

Korrelative elektrochemische Mikroskopie zur Aufklärung der lokalen ionischen und elektronischen Eigenschaften der Festkörper-Elektrolyt Zwischenphase in Li-Ionen-Batterien

Author(s): Santos, Carla S.; Botz, Alexander; Bandarenka, Aliaksandr S.; Ventosa, Edgar; Schuhmann, Wolfgang
Published in: Angewandthe Chemie, Issue 2, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202202744

Process-Product Interdependencies in Lamination of Electrodes and Separators for Lithium-Ion Batteries

Author(s): Ruben Leithoff, Arian Fröhlich, Steffen Masuch, Gabriela Ventura Silva, Klaus Dröder
Published in: MDPI Energies, Issue 2022, 2022, Page(s) 15(7), ISSN 1996-1073
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/en15072670

Electrochemical impedance spectroscopy error analysis and round robin on dummy cells and lithium-ion-batteries

Author(s): Kasper, Manuel; Leike, Arnd; Thielmann, Johannes; Winkler, Christian; Al-Zubaidi R-Smith, Nawfal; Kienberger, Ferry
Published in: Journal of Power Sources, Issue 536, 2022, ISSN 0378-7753
Publisher: Elsevier BV
DOI: 10.1016/j.jpowsour.2022.231407

Calibrated Electrochemical Impedance Spectroscopy and Time-Domain Measurements of a 7 kWh Automotive Lithium-Ion Battery Module with 396 Cylindrical Cells

Author(s): Kasper, Manuel; Moertelmaier, Manuel; Ragulskis, Mykolas; Al-Zubaidi R-Smith, Nawfal; Angerer, Johannes; Aufreiter, Mathias; Romero, Alberto; Krummacher, Jakob; Xu, Jianju; Root, David E.; Kienberger, Ferry
Published in: Batteries & Supercaps, Issue Volume 6, Issue 2, 2022, ISSN 2566-6223
Publisher: Chemistry Europe, Wiley-VCH
DOI: 10.1002/batt.202200415

High-Potential Test for Quality Control of Separator Defects in Battery Cell Production

Author(s): Louisa Hoffmann, Manuel Kasper, Maik Kahn, Georg Gramse, Gabriela Ventura Silva, Christoph Herrmann, Michael Kurrat, Ferry Kienberger
Published in: Batteries, Issue 7/4, 2021, Page(s) 64, ISSN 2313-0105
Publisher: MDPI
DOI: 10.3390/batteries7040064

Fast Li-ion Storage and Dynamics in TiO2 Nanoparticle Clusters Probed by Smart Scanning Electrochemical Cell Microscopy

Author(s): Batsa Tetteh, Emmanuel; Valavanis, Dimitrios; Daviddi, Enrico; Xu, Xiangdong; Santana Santos, Carla; Ventosa, Edgar; Martín-Yerga, Daniel; Schuhmann, Wolfgang; Unwin, Patrick R.
Published in: Angewandte Chemie - International Edition, Issue 62, 2023, Page(s) e202214493, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202214493

Multiplexed 16 × 16 Li-Ion Cell Measurements Including Internal Resistance for Quality Inspection and Classification

Author(s): Nawfal Al-Zubaidi R-Smith, Mykolas Ragulskis, Manuel Kasper, Sascha Wagner, Johannes Pumsleitner, Bob Zollo, Albert Groebmeyer, Ferry Kienberger
Published in: IEEE Transactions on Instrumentation and Measurement, Issue 70, 2021, Page(s) 1-9, ISSN 0018-9456
Publisher: Institute of Electrical and Electronics Engineers
DOI: 10.1109/tim.2021.3100331