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Renewable Power Generation by Solar Particle Receiver Driven Sulphur Storage Cycle

Deliverables

Project’s website, protected acronym, electronic communications network

Refers to Task 7.3 Aim: to enable efficient communication and exchange of confidential information among the partners as well as with the Project’s EU officer; to disseminate effectively the project’s results to a wide audience. Success indicators: Project’s website created and functional on schedule; increased visibility from outside the consortium.

Simplified and detailed chemical kinetics scheme

Refers to Task 5.3 Aim: to optimize the high power density combustion with respect to ultrafast mixing and heat release; to generate an overall combustion model; to develop a detailed kinetics scheme for the combustion of elemental sulphur with air and possibly water vapour incorporating NOx chemistry and a respective reduced scheme suitable for integration into a turbulent combustion model. Success indicators: positive evaluation of detailed and reduced chemical reaction schemes via key performance indicators, such as laminar flame velocity and emission characteristics, supported with experimental data.

Selection of burner concept and specification

Refers to Task 5.1 Aim: to elaborate a suitable burner concept for high power density sulphur combustion capable of integration within an over-all power generation and storage concept scheme. Success indicators: suitable conceptual parameters and safety concepts identified; type of peripheral components for supply of feed streams chosen; global process parameters and power modulation range required for integration into a power generation concept determined.

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Publications

Composite particles as active catalysts for the SO3 dissociation reaction of the thermochemical storage scheme based on elemental sulphur

Author(s): N.I. Tsongidis, K.G. Sakellariou, G. Karagiannakis, C. Pagkoura, A.G. Konstandopoulos
Published in: International Workshop on Solar Thermo-chemistry, Issue 12-14 September 2017, 2017

Speicherung von Solarenergie in elementaren Schwefel: Entwicklung eines mit solar aufgeheizten Partikeln betriebenen Schwefelsäurespaltungsreaktors Storage of solar energy as elemental sulphur: Development of a reactor for sulphuric acid splitting driven by solar heated particles

Author(s): N. Overbeck, D. Thomey, V. Thanda, C. Agrafiotis, M. Roeb, C. Sattler
Published in: Annual Meeting of ProcessNet Expert Group on Energy Chemical Engineering, Issue 7-8 March 2018, 2018

Development of catalytic particles for SO3 decomposition of the thermochemical energy storage scheme based on elemental sulfur

Author(s): K.G. Sakellariou, N.I. Tsongidis, G. Karagiannakis, C. Pagkoura, A.G. Konstandopoulos
Published in: 2017 NESTER School, Issue 6-16 November 2017, 2017

A computational investigation on the oxidation of sulfur

Author(s): N. Sebbar, J. W. Bozzelli, H. Bockhorn, D. Trimis
Published in: Third general Meeting, SMARTCATs, COST Action CM1401, Issue 25–27 October 2017, 2017

Bedarfsgerechte Solarstromproduktion durch Kombination von Partikeltechnologie und Schwefelspeicher-Kreisprozess On-demand solar power production by combining particle technology and sulphur storage cylce

Author(s): D. Thomey, C. Agrafiotis, N. Overbeck, B. Gobereit, C. Frantz, T. Baumann, M. Roeb, R. Uhlig, C. Sattler
Published in: 20th Solar Colloquium Cologne, Issue 20 July 2017, 2017

A thermochemical study on the primary oxidation of sulfur

Author(s): N. Sebbar, J.W. Bozzelli, H. Bockhorn, D. Trimis
Published in: Proceeding of the Tenth Mediterranean Combustion Symposium – MCS10, Issue 17–21 September 2017, 2017

A DFT and ab-initio study on the primary oxidation mechanism of S2

Author(s): N. Sebbar, J. W. Bozzelli, H. Bockhorn, D. Trimis
Published in: 8th European Combustion Meeting, Issue 18-21 April 2017, 2017

Sulphur – solar fuel for on demand power generation

Author(s): D. Thomey, C. Agrafiotis, N. Overbeck, M. Roeb, C. Sattler
Published in: International Workshop on Solar Thermo-chemistry, Issue 12-14 September 2017, 2017

Composite particles as active catalysts for the SO3 dissociation reaction of the thermochemical storage scheme based on elemental sulfur

Author(s): N.I. Tsongidis, G. Karagiannakis, K.G. Sakellariou, C. Pagkoura, A.G. Konstandopoulos, D. Janus, M. Zagaja, D. Pomykalska
Published in: Solar PACES 2017, Issue 26-29 September 2017, 2017

Solar sulphur – fuel for on-demand and carbon-free power production

Author(s): D. Thomey, C. Agrafiotis, N. Overbeck, M. Roeb, C. Sattler
Published in: 2nd Middle East Sulphur, Issue 18-20 March 2018, 2018

The EU Horizon 2020 project PEGASUS and its role in the CSP

Author(s): D. Thomey, C. Agrafiotis, N. Overbeck, M. Roeb, C. Sattler
Published in: CSP Today Sevilla 2017, Issue 21-22 November 2017, 2017

Sulfur combustion as closing step in a sulfur based solar-thermal cycle

Author(s): N. Sebbar, S. Harth, M. Fedoryk, H. Heidarifatasmi, F. Zhang, J. W. Bozzelli, H. Bockhorn, D. Trimis
Published in: COST Action SMARTCATS – 1st international conference on smart energy carriers, Issue 21-23 Jan. 2019, 2019

Oxide particles as combined heat storage medium and sulphur trioxide decomposition catalysts for solar hydrogen production through sulphur cycles

Author(s): C. Agrafiotis, D. Thomey, L. de Oliveira, C. Happich, M. Roeb, C. Sattler, N. I. Tsongidis, K. G. Sakellariou, C. Pagkoura, G. Karagiannakis, A. G. Konstandopoulos, D. Pomykalska, M. Zagaja and D. Janus
Published in: 9th International Conference on Hydrogen Production (ICH2P-2018), Issue 16-29 Jul. 2018, 2018

Combustion Processes in Energy Conversion for Use of Renewable Energies

Author(s): N. Sebbar, T. Zirwes, P. Habisreuther, H. Bockhorn and D. Trimis
Published in: 7th annual meeting of KIT Energy Center, Issue 26 Jun. 2018, 2018

Sulphur Combustion at High Power Density for a Sulphur-based Energy Storage for Solar Power

Author(s): M. Fedoryk, S. Harth, N. Sebbar, D. Trimis
Published in: 7th annual meeting of KIT Energy Center, Issue 26 Jun. 2018, 2018

Investigation of S2 + air combustion

Author(s): N. Sebbar, T. Zirwes, P. Habisreuther, H. Bockhorn, D. Trimis
Published in: Joint Meeting of the German and Italian Sections of the combustion Institute, Issue 23-26 May 2018, 2018

A Thermochemical and Kinetic Study of Species and Reactions Occurring in the S-N-O System

Author(s): N. Sebbar, J. W. Bozzelli, H. Bockhorn, D. Trimis
Published in: 9th European Combustion Meeting, Issue 14-17 Apr. 2019, 2019

Numerical simulation of sulfur combustors with high-power-density

Author(s): F. Zhang, H. Heidarifatasmi, T. Zirwes, M. Fedoryk, S. Harth, N. Sebbar, P. Habisreuther, D. Trimis, H. Bockhorn
Published in: 9th European Combustion Meeting, Issue 14-17 Apr. 2019, 2019

Ignition behaviour of sulfur in air based on modified reaction kinetics

Author(s): T. Zirwes, N. Sebbar, P. Habisreuther, S. Harth, F. Zhang, H. Bockhorn, D. Trimis
Published in: 11th Mediterranean Combustion Symposium, Issue 16-20 Jun. 2019, 2019

Entwicklung von Schwefelbrennern mit hohen Leistungsdichten Developent of sulphur burners with high power density

Author(s): M. Fedoryk, F. Zhang, H. Heidarifatasmi, T. Zirwes, N. Sebbar, S. Harth, D. Trimis
Published in: Jahrestreffen der ProcessNet Fachgruppe Hochtemperaturtechnik, Issue 2-3 Apr. 2019, 2019

A Thermochemical Study of Reactions Occurring in the S-N-O System

Author(s): N. Sebbar, J. W. Bozzelli, H. Bockhorn, D. Trimis
Published in: 11th Mediterranean Combustion Symposium, Issue 16-20 Jun. 2019, 2019

Materials for High Temperature Solar Chemistry Applications: Energy Storage & Solar Fuels

Author(s): Karagiannakis G.
Published in: 47th IUPAC World Chemistry Congress, Issue July 5-12 2019, 2019

Solar-thermal power and chemical engineering: new Opportunities

Author(s): M. Roeb
Published in: Summer School – Making Business with Green Chemistry & Sustainable Energy, Issue 22-26 Jul. 2019, 2019

Schwefelbrenner mit hoher Leistungsdichte für Solarkraftwerke mit Schwefelspeicherzyklus Sulphur burner wiht high power desity for solar power plants with sulphur storage cycle

Author(s): D. Trimis, S. Harth, N. Sebbar, M. Fedoryk, H. Heidarifatasmi, F. Zhang
Published in: 22nd Solar Colloquium Cologne, Issue 10 Jul. 2019, 2019

Iron oxide-based particles for high temperature thermochemical energy storage via the elemental sulfur thermochemical cycle

Author(s): Nikolaos I. Tsongidis, George Karagiannakis, Kyriaki G. Sakellariou, Chrysa Pagkoura, Athanasios G. Konstandopoulos
Published in: SOLARPACES 2018: International Conference on Concentrating Solar Power and Chemical Energy Systems, 2019, Page(s) 210009
DOI: 10.1063/1.5117758

Numerical Investigation of a Sulfur Combustor

Author(s): F. Zhang, H. Heidarifatasmi, S. Harth, T. Zirwes, M. Fedoryk, N. Sebbar, D. Trimis
Published in: 29. Deutscher Flammentag, Issue 17-18 Sep. 2019, 2019

Solar Energy Conversion and Storage through Sulphur-Based Thermochemical Cycles Implemented on Centrifugal Particle Receivers

Author(s): Christos Agrafiotis, Dennis Thomey, Lamark de Oliveira, Nicolas Overbeck, Vamshi Krishna Thanda, Martin Roeb, Christian Sattler
Published in: Proceedings of 25th SolarPACES Conference, Issue 1-4 Oct. 2019, 2019

BrightSource's optimized solar field layout performance: General considerations and case study

Author(s): Morag Am-Shallem
Published in: 3rd CSP Focus Innovation 2019, Issue 24-25 Oct. 2019, 2019

Safety Issues in Heliostat Movement in The Solar Field

Author(s): Jonny Gulayev
Published in: 3rd CSP Focus Innovation 2019, Issue 24-25 Oct. 2019, 2019

Recent trends in Thermo-Chemical heat Storage

Author(s): Karagiannakis G., Lorentzou S., Pagkoura C., Sakellariou K.G., Konstandopoulos A.G.
Published in: 13th Pacific Rim Conference of Ceramic Societies, Issue October 27 - November 1, 2019, 2019

Sulphur – solar fuel for on demand power generation

Author(s): Dennis Thomey, Christos Agrafiotis, Vamshi Krishna Thanda, Lamark de Oliveira, Kai-Peter Eßer, Martin Roeb, Christian Sattler
Published in: IGSTC Workshop, Cologne, Issue 17-18 Oct. 2019, 2019

A thermochemical study on the primary oxidation of sulfur

Author(s): N. Sebbar, J.W. Bozzelli, H. Bockhorn, D. Trimis
Published in: Combustion Science and Technology, 2018, Page(s) 1-15, ISSN 0010-2202
DOI: 10.1080/00102202.2018.1455134

Solar hydrogen production via sulphur based thermochemical water-splitting

Author(s): Christian Sattler, Martin Roeb, Christos Agrafiotis, Dennis Thomey
Published in: Solar Energy, Issue 156, 2017, Page(s) 30-47, ISSN 0038-092X
DOI: 10.1016/j.solener.2017.05.060

S 2 + Air Combustion: Reaction Kinetics, Flame Structure, and Laminar Flame Behavior

Author(s): N. Sebbar, T. Zirwes, P. Habisreuther, J. W. Bozzelli, H. Bockhorn, D. Trimis
Published in: Energy & Fuels, Issue 32/10, 2018, Page(s) 10184-10193, ISSN 0887-0624
DOI: 10.1021/acs.energyfuels.8b01019

Oxide particles as combined heat storage medium and sulphur trioxide decomposition catalysts for solar hydrogen production through sulphur cycles

Author(s): Christos Agrafiotis, Dennis Thomey, Lamark de Oliveira, Christoph Happich, Martin Roeb, Christian Sattler, Nikolaos I. Tsongidis, Kyriaki G. Sakellariou, Chrysoula Pagkoura, George Karagiannakis, Athanasios G. Konstandopoulos, Daria Pomykalska, Marek Zagaja, Dariusz Janus
Published in: International Journal of Hydrogen Energy, Issue 44/20, 2019, Page(s) 9830-9840, ISSN 0360-3199
DOI: 10.1016/j.ijhydene.2018.11.056

Thermochemical Production of Sulfur as Solar fuel: Design and development of moving bed heat exchanger for sulfuric acid evaporation heated by ceramic particles

Author(s): Vamshi Krishna Thanda Supervisors: N. Overbeck, D. Thomey
Published in: Issue 23 Jul. 2018, 2018, Page(s) 98

Techno-economic study of a concentrated solar thermal plant with sulphur as thermochemical energy storage for baseload power generation and sulphuric acid recycling

Author(s): Andreas Rosenstiel Supervisor: D. Thomey
Published in: Issue 31 May 2018, 2018, Page(s) 95

Process modelling of sulphur based thermochemical cycle S/H2SO4 for renewable power production

Author(s): Davide Campagna Tutors: Annarita Salladini, Gaetano Iaquaniello
Published in: Issue 23 July 2018, 2018, Page(s) 108

Detailed engineering of a particle-heated lab-scale reactor for the decomposition of sulphuric acid

Author(s): Lutz Eric Mevißen Supervisor: D. Thomey
Published in: Issue 15 Oct. 2019, 2019, Page(s) 109