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CO2 to light olefins conversion by cascade reactions over bifunctional nanocatalysts: an ‘all X-ray’ approach

Objective

In a waste-to-value perspective, CO2 can represent a sustainable carbon source to produce light olefins, representing key building blocks for petrochemical industry. CASCADE-X proposes an ultimate approach to directly convert CO2 to light olefins through cascade reactions over a bi-functional catalyst, obtained by molecular scale integration of an active metal alloy for the CO2-to-methanol reaction onto a zeotype catalyst for selective methanol-to-olefins conversion. Such a single-reactor cascade approach enables a simplified process scheme while overcoming the thermodynamic restrictions of the methanol synthesis by its sequential conversion. The action will generate fundamental knowledge on properties-performances relationships for the combined system, providing a rational for the optimization of catalyst and process conditions, as well as an improved understanding of key fundamental issues in both hydrogenation and methanol-to-olefins chemistry (restructuring, deactivation mechanisms, confinement effects). These goals will be pursued by an ‘all-X-ray’ approach, synergizing in situ and operando X-ray absorption spectroscopy and diffraction/scattering at the laboratory and large-scale facility level in combination with complementary physico-chemical methods, to identify activity/selectivity/stability descriptors for the bifunctional catalyst. Multi-modal synchrotron nano-mapping of individual catalyst particles will elucidate the space-resolved dynamics of restructuring and deactivation phenomena. Integrating the applicant’s experience in X-ray spectroscopy, the Host’s excellence in structural analysis, testing and rational optimization of zeotype catalysts, as well as the industrial know-how of the private sector partner (a leading Company in recycling and manufacturing precious metal catalysts, where a Secondment is planned), CASCADE-X provides a unique platform to diversify the proponent’s individual competences and to promote trans-sectoral knowledge transfer.

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Keywords

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Programme(s)

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Topic(s)

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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) H2020-MSCA-IF-2017

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Coordinator

UNIVERSITETET I OSLO
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 196 400,40
Address
PROBLEMVEIEN 5-7
0313 Oslo
Norway

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Region
Norge Oslo og Viken Oslo
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 196 400,40
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