New Approaches to Develop Enhanced Safety Materials for Gen 3 Li-Ion Batteries for Mobility Applications (Batt4EU Partnership)

This topic aims at developing safer materials for high-performing cells by targeted modification in main cell components, namely the cathode, anode, separator and electrolyte. Solutions to common safety hazards have to be covered through a comprehensive design of new materials for at least three of following components:

• New cathode materials with no exothermal decomposition/reactions, reduced probability for oxygen and other gasses release, and preventing corrosion at current collector. Development can include the following approaches/strategies at different levels:
  • Doping strategies or surface coating materials leading to more robust and effective cathode electrolyte interphase (CEI).
  • Design of high-capacity cathode materials based on safer chemistries (e.g. stabilized Li-rich layered oxides, disordered rock salts, polyanionic materials…).
  • Design high-voltage cathodes and high voltage anodes in order to combine them in a high energy cell, with sufficiently high operating voltage to avoid stripping/plating of lithium.
  • Innovative approaches of cathode structuring to mitigate heat generation, including with toxic gas releases, in abuse conditions.
• New stable anode materials and electrode designs with non-swelling, or low degree of expansion over the whole cell lifetime, with no decomposition/exfoliation, high resistance against Li-dendrite formation – specially at high anode rate capabilities, and favouring the formation of a thermally stable, and low-resistivity SEI. Development can include the following approaches/strategies at different levels:
  • Design and development of new systems with higher standard potential compared to lithium stripping/plating. (High SiOx, Si/C, etc. content).
  • Surface coating materials for more robust and effective SEI.
  • New approaches to minimize material/anode swelling and expansion during cycling, including anode manufacturing (polymeric and ceramic coating-based approaches, etc.) and structuring the anode-current collector interface.
• New electrolyte formulations with shear thickening, flame retardant and over-charge/discharge properties, maintained high ionic conductivity, broad electrochemical stability i.e. voltage-operating window, and high onset point for Li-dendrite formation, SEI decomposition and CEI effectiveness. Development can include the following approaches/strategies at different levels:
  • (Multi-)functional additives for SEI and CEI stabilisation and protection on anode and cathode such as flame-retardant additives or solvents, ionic conductivity boosters, stability window promoters, etc.
  • Addition of selective particles (i.e. oxides, etc.) to hinder mechanical abuse and improve shear thickening behaviour.
• New separator materials with flame retardant and improved ion transport capabilities, high melting point, and mechanical stability
• New binder materials with thermal, mechanical and electrochemical stability (self-healing systems), low ionic and electrical resistance, improved adhesion and cohesion, and preventing swelling and porosity reduction in electrodes.

Projects need to justify the relevance of the selected components which will be addressed and how the new materials, and the combination of them, will lead to better safety outcomes. To the extent possible the safety and sustainability of developed materials should be assessed in alignment with the Commission Recommendation on safe and sustainable by design chemicals and materials[[Commission Recommendation (EU/2022/2510) establishing a European assessment framework for ‘safe and sustainable by design’ chemicals and materials.]].

Plans for the exploitation and dissemination of results for proposals submitted under this topic should include a strong business case and sound exploitation strategy, as outlined in the introduction to this Destination. The exploitation plans should include preliminary plans for scalability, commercialisation, and deployment (feasibility study, business plan).

In order to achieve the expected outcomes, international cooperation is encouraged, in particular with the USA.

Projects may collaborate and/or contribute to the activities of the Coordination and Support Action defined under the topic HORIZON-CL5-2022-D2-01-08.

This topic implements the co-programmed European Partnership on Batteries (Batt4EU). As such, projects resulting from this topic will be expected to report on the results to the European Partnership on Batteries (Batt4EU) in support of the monitoring of its KPIs.