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Content archived on 2024-06-16

Stereoselective Fe- and Co-catalyzed Oxidation and Peroxidation of Hydrocarbons

Objective

Selective catalytic oxidations of organic molecules are among the most important industrial chemical processes. Chemical raw materials are principally hydrocarbons which are the product of petrochemical production. Due to their inert nature, their selective functionalization is a key objective of research in academia and industry. The aim of the project is the development of a novel class of homogeneous oxidation catalysts which are effective in the stereo-selective allylic oxidation of alkenes. In contrast to the majority of the previously studied copper complexes, these will be iron (and cobalt) based. Beyond the narrower goals of the proposed research, they provide the potential access to catalytic systems for the controlled oxidation of prochiral alkanes. The key to the practical implementation of the research program is the development of two novel classes of meridianally coordinating chiral ligands which are potentially suitable for enantio-selective transformations. The approach combines design- and diversity-driven elements and the efficiency of the iron catalysts will be tested with respect to a number of standard reactions which allow the comparison with previously reported chiral catalysts. High throughput analytical methods are will be extensively used in the optimization of catalyst performance.

Fields of science (EuroSciVoc)

CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

FP6-2002-MOBILITY-5
See other projects for this call

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

EIF - Marie Curie actions-Intra-European Fellowships

Coordinator

RUPRECHT-KARLS-UNIVERSITAET HEIDELBERG
EU contribution
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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